Journal of Chemical and Engineering Data, Vol.54, No.2, 485-490, 2009
Ternary Diffusion Coefficients of Cyclohexane plus Toluene plus Methanol by Taylor Dispersion Measurements at 298.15 K. Part 2. Low Toluene Area Near the Binodal Curve
The concentration dependence of the mutual diffusion coefficients in the ternary liquid mixture cyclohexane (1) + toluene (2) + methanol (3) is determined at 298.15 K by the Taylor dispersion technique along three concentration paths of a constant toluene mole fraction of x(2) = 0.05, x(2) = 0. 10, and x(2) = 0.20, ranging from the binary subsystems toward the liquid-liquid phase boundary of the ternary system. The four elements of the matrix of mutual diffusion coefficients, the corresponding eigenvalues, and the determinant of the matrix are given.