The excess molar Volumes (V(E)) and viscosity deviations (Delta eta) have been calculated from experimental density (rho) and viscosity (eta) data of the binary mixtures of 1,3-dioxolane (DO) with 2-methoxyethanol (ME), 2-ethoxyethanol (EE), 2-butoxyethanol (BE). 2-propylamine (PA), and cyclohexylamine (CA) measured over the entire range of composition tit 298.15 K. Moreover, deviations in isentropic compressibility (Delta K(S)) and molar refraction (Delta R) have been calculated from ultrasonic speed of sounds (u) and refractive indices (n(D)) of the mixtures, respectively. The excess or deviation properties were fitted to the Redlich-Kister polynomial equation to derive the adjustable parameters (A(lambda)) and corresponding standard deviations (sigma).