Consistent vapor-liquid equilibria (VI-E) data at 100 kPa have been determined for the ternary system cyclohexane + cyclohexene + 2-methoxyethanol and two Constituent binary systems: cyclohexane + 2-methoxyethanol and cyclohexene + 2-methoxyethanol. Both binary systems deviate remarkably from ideal behavior presenting a minimum boiling point azeotrope. The VLE data have been correlated by the Wilson, UNIQUAC, and NRTL equations. The ternary system does not present an azeotrope and is well predicted from binary interaction parameters. Prediction with the UNIFAC method has been also obtained.