Journal of Chemical and Engineering Data, Vol.55, No.2, 595-599, 2010
Dependence against Temperature and Pressure of the Isobaric Thermal Expansivity of Room Temperature Ionic Liquids
The isobaric thermal expansivity alpha(p) in the temperature and pressure intervals of (278.15 to 348.15) K and (5 to 50) MPa is reported for an assorted set of room temperature ionic liquids (RTILs) using a calorimetric method with an uncertainty of 2 %. The RTILs were selected to represent some of the most widely studied anions and cations; 1-butyl-3-methylpyridinium tetrafluoroborate [C(4)mpyr][BF(4)], 1-ethyl-3-methylimidazolium tetrafluoroborate [C(2)mim][BF(4)], 1-hexyl-3-methylimidazolium tetrafluoroborate [C(6)mim][BF(4)], 1-octyl-3-methylimidazolium tetrafluoroborate [C(8)mim][BF(4)], 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide [C(2)mim][NTf(2)], and 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide [C(6)mim][NTf(2)] are analyzed. The same general trends were obtained for the studied liquids, although differences are found both in the magnitude and in the alpha(p) behavior against temperature and pressure.