The vapor pressures of condensed phases of methyl p-methylbenzoate and methyl p-(dimethylamino)benzoate were measured in the temperature ranges (269.3 to 357.0) K and (325.0 to 390.4) K, respectively, using a static method. The Knudsen mass-loss effusion technique was also used to study the vapor pressures as function of temperature of the crystals of methyl p-(dimethylamino)benzoate in the pressure range (0.1 to 1) Pa. The results obtained for each compound enabled the determination of the standard molar entropies and enthalpies of sublimation and of vaporization at T = 298.15 K as well as phase diagram representations of the (p,T) experimental data. The temperatures and molar enthalpies of fusion were determined using differential scanning calorimetry and were compared with the values derived from the vapor pressure measurements. The enthalpies of the intermolecular hydrogen bonds O-H center dot center dot center dot O in the crystalline phase of the parent substituted benzoic acids were calculated.