The densities and viscosities of 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl))imide ([EMIM][NTf2]) + N-methyl-2-pyrrolidone (NMP) and [EMIM] [NTf2] + ethanol mixtures were investigated over the mole fraction range from (0.1 to 0.9) and at temperatures from (293.15 to 323.15) K at intervals of 5 K. The densities can be well-represented by the quadratic equation, and the viscosities can be represented in the form of the Vogel equation. The excess molar volumes (V-E) and viscosity deviations (Delta eta) were calculated, and the results were fitted to the Redlich-Kister equation using a multiparametric nonlinear regression method. The estimated parameters of the Redlich-Kister equation and standard deviation were also presented. The results showed that the densities and viscosities were dependent strongly on NMP or ethanol content. Comparatively, the viscosity deviation Delta eta was more sensitive to temperature than the excess molar volume V-E.