The ceramics with 0.90Pb(Zr0.50Ti0.50)O-3-0.07Pb(Mn1/3Nb2/3)O-3-0.03Pb(Ni1/2W1/2)O-3 were prepared by adding Cr2O3. The effects of Cr2O3 doping on the phase structure, the microstructure and the electrical properties of ceramics were investigated. Meanwhile, the temperature stabilities of the resonant frequency (f(r)) and the electromechanical coupling factor (K-p) were studied. The results showed that the better temperature stability could be obtained at x = 0.2 wt.% when the calcining temperature was 800 degrees C and the sintering temperature was 1150 degrees C. The parameters were Delta f(r)/f(r25) (degrees C) = -0.17% and Delta K-p/K-P25 (degrees C) = -1.39%. Moreover, the optimized electrical properties were also achieved, which were K-p = 0.54, Q(m) = 1730, d(33) = 330 pC/N, 2078 and tan delta = 0.0052. The optimized properties make the ceramics with this composition to be a good candidate for high power piezoelectric transformers applications. (c) 2007 Elsevier Ltd. All rights reserved.