The structural, electrical and magnetic properties of LaCr0.5M0.5O3 (M = Cr3+, Cu2+ and Fe3+) synthesized by a sol-gel technique were studied. The X-ray diffraction pattern shows the structure to be orthorhombic and the size of the particles is around 100 nm as seen from the TEM images. The effects of Cu2+ and Fe3+ on the electrical properties of LaCrO3 were studied using impedance spectroscopy at room temperature (RT). The properties of LaCr0.5Cu0.5O3 were studied over a wide range of temperature from RT to 533 K. A maximum conductivity of 1.7 x 10(-3) S cm(-1) Was observed for LaCr0.5Cu0.5O3 at a measured temperature of 533 K. The impedance spectra indicate a negative temperature coefficient of resistance (NTCR) and also imply the conduction is through bulk of the material. The magnetic studies performed using a SQUID magnetometer interpret the antiferromagnetically ordered LaCrO3 to behave ferromagnetically on the addition of Cu2+ and Fe3+, and the magnetization was found to be enhanced in the LaCr0.5Fe0.5O3. (C) 2012 Elsevier Ltd. All rights reserved.