Films were made from blends of high methoxy pectin and high amylose starch gelatinized in a microwave oven in the presence and absence of glycerol at times ranging from 10 to 105 s. Three thermodynamic transitions were observed when storage modulus, loss modulus, and loss tangent were plotted against temperature. All three transitions gave minima when the transition temperature was plotted against time of gelatinization. Overall, there were only modest changes in these moduli over the range of gelatinization times studied, with little difference between films made with the starch gelatinized in either the presence or absence of glycerol. Starch granules were found to disappear at gelatinization times between 20 and 30 s, although much smaller starch particles seemed to recur at gelatinization times of 75 s and above. The minima found in the transition temperature and modulus plots were believed to result from a minimum in the amount of intermolecular interactions between the starch molecules.