화학공학소재연구정보센터
Propellants Explosives Pyrotechnics, Vol.30, No.5, 381-385, 2005
Analytic model of reactive flow
A simple analytic model allows prediction of rate constants and size effect behavior before a hydrocode run, if size effect data exist. It utilizes detonation velocity, average detonation rate, pressure and energy at infinite radius. This allows the derivation of a generalized radius, which becomes larger as the explosive becomes more non-ideal. The model is applied to near-ideal PBX 9404, in-between ANFO and most non-ideal AN. The power of the pressure declines from 2.3, and 1.5 to 0.8 across this set. The power of the burn fraction, F is 0.8, 0 and 0, so that an F-term is important only for the ideal explosives. The size effect shapes change from concave-down to nearly straight to concave-up. Failure is associated with ideal explosives when the calculated detonation velocity turns in a double-valued way. The effect of the power of the pressure may be simulated by including a pressure cut-off in the detonation rate. The model allows comparison of a wide spectrum of explosives providing that a single detonation rate is feasible.