Przemysl Chemiczny, Vol.87, No.3, 278-283, 2008
Biodegradation of polycyclic aromatic hydrocarbons in bottom sediments in presence of calcium peroxide
Sixteen polycyclic arom. hydrocarbons (PAH) were biodecompd. in bottom sediments for 150 days with CaO2 as the oxidn. agent both under laboratory conditions (CaO2 dosis 300 g/m(2)) and in 2 metal chambers (CaO2 doses 200 and 100 g/m(2)) located in the Rybnik water basin. The degree of overall removal of the PAHs after 150 days was 83%, 68% and 60%, resp. The concn. of fluoranthene (the most dominant PAH) decreased in the laboratory tests from 13 mg/kg down to about 3 mg/kg (dry mass) after 15 days of the expt. In the chamber tests, the concn. decreased down to 6-8 mg/kg (dry mass) after 30 days. The decompn. kinetics was described with the 2-nd order equation. Fundamentals of the process were also outlined.