Solar Energy Materials and Solar Cells, Vol.90, No.10, 1504-1512, 2006
Ion energy dependence of nanodol formation by nitrogen-bombarded InP
When InP is bombarded with noble gas ions or nitrogen ions, nano-scaled sputter cones appear on the surface. In this study, we report on the ion energy dependence of the surface topography due to nitrogen ion bombardment. InP(I 0 0) substrates were bombarded with 1-5 keV N-2(+) ions at an angle of incidence of 41 degrees with respect to the normal. The fluence was fixed at 5 x 10(16) N-2(+) cm(-2) The topographies of the virgin and bombarded samples were investigated by AFM (atomic force microscopy) and high-resolution SEM (scanning electron microscopy). There are similarities between the topographies of the nitrogen-bombarded surfaces to those reported for noble gas ion bombardment. The AFM-measured topographies were quantified in terms of the root mean square (rms) roughness. The rms of 12 roughness initially decreases from a high value at 0.5 keV per nitrogen atom to reach a minimum somewhere between 1.5 and 2 keV per nitrogen atom. The results are compared to the results reported for noble gas ion-bombarded InP and to the standard theories in this field. In general, the rms roughness as a function of ion energy is ion mass dependent, in agreement with results reported for ripples on Si and GaAs. However, there seems to be only a slight dependence on the chemical reactivity of the bombarding ions with the InP substrate. No ripples were observed on the samples. (c) 2005 Elsevier B.V. All rights reserved.
Keywords:topography;morphology;nitrogen bombardment;AFM;sputter cones;bombardment-induced ripples;nano-technology;ion bombardment;InP;indium phosphide