A new type of stainless steel mesh-based flexible quasi-solid dye-sensitized solar cell (DSSC) was designed and fabricated by using electrospun TiO(2) nanofibers web as a light scattering layer and stainless steel foil coated with polypyrrole (PPy) nanoparticles as counter electrode. The photovoltaic performance measurements showed that electrospun TiO(2) nanofibers web was propitious to light harvesting ability and energy conversion efficiency. Cyclic voltammogram measurement revealed that PPy electrode possessed smaller charge-transfer resistance and higher electrocatalytic activity for the I(2)/I(-) redox reaction than that of Pt electrode. A overall energy conversion efficiency (eta) of 2.36% was obtained based on a DSSC with N719 dye as sensitizer and PPy nanoparticles coated on the stainless steel foil as counter electrode, which attained 84% of the value (2.80%) of the quasi-solid DSSC with Pt foil as counter electrode. (C) 2010 Elsevier B.V. All rights reserved.