Hexagonal tungsten bronze (HTB) nanocrystal and TiO(2) nanoparticles were assembled into thin films by layer-by-layer self-assembly method HTB nanocrystals were synthesized by hydrothermal route at 155 degrees C UV-Vis spectra showed that the HTB/TiO(2) films exhibit a linear increase in film thickness with assembly exposure steps The electrochromic property of the film was carefully investigated. Cyclic voltammetry indicated that the redox peak was around -05 V The electrochromic contrast, coloration efficiency, switching speed, stability and optical memory were carefully investigated The films vary from white to blue and finally dark brown The electrochromic contrast is 63 9% at 633 nm. The coloration efficiency of the films is relatively high The response time is less than 3 s. (C) 2010 Elsevier B V All rights reserved.