Thin Solid Films, Vol.519, No.14, 4447-4450, 2011
Effect of filament temperature and deposition time on the formation of tungsten silicide with silane
The effect of filament temperature and deposition time on the formation of tungsten silicide upon exposure to the SiH(4) gas in a hot wire chemical vapor deposition process was studied using the techniques of cross-sectional scanning electron microscopy and Auger electron spectroscopy. At a relatively low temperature of 1500 degrees C, the decomposition of WSi(2) phase and the diffusion of Si towards the silicide/W interface produce a thick W(5)Si(3) layer. The diffusional nature leads to a parabolic rate law for silicide growth. An exponential decrease of silicide thickness with temperature between 1600 and 2000 degrees C illustrates the dominance of Si evaporation at higher temperatures (T >= 1600 degrees C) over the silicide formation. (C) 2011 Elsevier B.V. All rights reserved.