Influences of the temperature (T-s) for spray pyrolysis deposition of TiO2 blocking layer (BL) using titanium diisopropoxide bis(acetylacetonate) (TAA) as a precursor and the temperature (T-p) for post-annealing of the BL films on the resulting BL film morphology and photovoltaic performance of solid-state dye-sensitized solar cells (SDSC) are investigated. A T-s ranging from 300 to 400 degrees C is found preferable for the formation of BL films with smooth surface and dense grain packing. A T-s lower than 300 degrees C results in insufficient decomposition of the TAA precursor and is unable to form smooth BL films, while a T-s over 400 degrees C leads to loosely packed grain in BL films. Power conversion efficiency (PCE) of similar to 4.0% is obtained for SDSC devices with BL films prepared at a T-s in the range of 300-450 degrees C. High temperature post-annealing (T-p = 500-550 degrees C) of the BL films prepared at a low T-s, such as 300 degrees C, can improve the PCE up to 4.6%. The improvements are considered due to the higher purity, increased crystallinity, and retained high grain packing density of the post-annealed BL films, which facilitate charge transport and suppress charge recombination. (C) 2011 Elsevier B.V. All rights reserved.