화학공학소재연구정보센터
Thin Solid Films, Vol.520, No.8, 3133-3138, 2012
Low temperature Si:C co-flow and hybrid process using Si3H8/Cl-2
In this paper we demonstrate a Si3H8/SiH3CH3/PH3/Cl-2 based co-flow process and a "hybrid" co-flow process with interruptions of the deposition. The motivation for the work stems from the desire to improve manufactur-ability through higher growth rates and higher etch rates commensurate with the drive to lower thermal budgets of integration of Complementary Metal Oxide Semiconductor and memory platforms. For high volume manufacturing, high selective epitaxial growth rates are necessary for enhanced throughput and low cost of ownership. Both high growth rate and low temperatures enable sufficiently high substitutional carbon levels [C] sub in dilute Si:C alloys. The hydride deposition gases Si3H8, SiH3CH3 and PH3 and the etch gas Cl-2 were kept separate in the pressurized gas supply lines and injected separately into the reaction chamber thus avoiding premature chemical reactions. The importance and the role of a suitable inert carrier gas are emphasized. (C) 2011 Elsevier B.V. All rights reserved.