화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.18, No.6, 2092-2102, November, 2012
DOI10.1016/j.jiec.2012.06.003  Export Citation
Effect of process conditions on the surface reaction rates and catalytic performance of MgO supported Fe-Co-Mn catalyst for CO hydrogenation
M. Arsalanfar, A.A. Mirzaei†, H.R. Bozorgzadeh1, and H. Atashi2
  • Department of Chemistry, Faculty of Sciences, University of Sistan and Baluchestan, Zahedan 98135-674, Iran
  • 1Gas Division, Research Institute of Petroleum Industry (RIPI), Tehran, Iran
  • 2Department of Chemical Engineering, Faculty of Engineering, University of Sistan and Baluchestan, P.O. Box 98164-161, Zahedan, Iran
E-mail:
The Fe-Co-Mn/MgO catalyst was prepared using co-precipitation procedure; effects of reaction conditions on the catalytic performance for Fischer.Tropsch synthesis have been investigated. Experiments were carried out under a wide range of reaction conditions including reaction temperature of 473.673 K, pressure of 1-10 bar, H2/CO feed molar ratio of 1-4 and space velocity of 3150-7200 h^(-1). We also reported further results regarding the effect of various operational conditions on different surface reaction rates. It was found that the optimum operational conditions are H2/CO = 2/1, GHSV = 4500 h^(-1), T = 573 K and P = 1 bar. Characterization of both precursor and calcined catalysts was carried out using XRD, SEM, BET and TPR.
Keywords:Fe-Co-Mn catalyst;Co-precipitation;Operational conditions;CO hydrogenation;Characterization
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