Adsorption of 2-mercaptopyridine and 4-mercaptopyridine on a silver surfaces investigated by SERS spectroscopy

Won Hui Do; Chul Jae Lee; Dong Yeub Kim; Maeng Joon Jung

Journal of Industrial and Engineering Chemistry, Vol.18, No.6, 2141-2146, November, 2012

DOI10.1016/j.jiec.2012.06.009 Export Citation

Adsorption of 2-mercaptopyridine and 4-mercaptopyridine on a silver surfaces investigated by SERS spectroscopy

Won Hui Do, Chul Jae Lee¹, Dong Yeub Kim¹, and Maeng Joon Jung^{2, †}

Department of Chemistry, Kyungpook National University, Daegu 702-701, Republic of Korea
¹School of Chemical Industry, Yeungnam College of Science & Technology, Daegu 705-703, Republic of Korea
²School of Nano & Materials Science Engineering, Kyungpook National University, Sangju 742-711, Republic of Korea

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In this study, the 2-mercaptopyridine (2-MPY) and 4-mercaptopyridine (4-MPY) on to silver mirror and silver sol substrates have been studied by surface enhanced Raman scattering(SERS). The surface enhanced properties of 2-MPY and 4-MPY showed that the substrate of silver mirror was superior to the sliver sol. The silver mirror and silver sol substrates were prepared by Tollen’s and gamma irradiation method respectively. UV-visible spectra indicate that Ag nanoparticles were produced by this method. Considerable differences were found in the SERS spectra of 2-MPY and 4-MPY molecules onto silver mirror and silver sol substrates. From the analysis of the SERS data, it was evidenced that 2-MPY was chemisorbed through its S atom to Ag surfaces at a perpendicular orientation, whereas 4-MPY was bonded to Ag surface via the S atom and N atom assuming a tilted orientation.

Keywords:SERS;2-Mercaptopyridine;4-Mercaptopyridine;Tollen’s method;Gamma irradiation

[References]

Jeanmaire DL, Van Duyne PR, Journal of Electroanalytical Chemistry., 84, 1 (1977)
Albrecht MG, Creighton JA, Journal of the American Chemical Society., 99, 5215 (1977)
Van Duyne PR, in: Moore CB (Ed.),, Chemical and Biochemical Applications of Lasers, vol. IV, Academic Press, New York, 101 (1979)
Furtak TE, in: Chang RK (Ed.), Surface Enhanced Raman Scattering, Plenum Press, New York, 45 (1982)
Moskovits M, Reviews of Modern Physics., 57, 783 (1985)
Fleischmann M, Hendra DJ, McQuillan AJ, Chemical Physics Letters., 26, 163 (1974)
Saito Y, Wang JJ, Smith DA, Batchelder DN, Langmuir, 18(8), 2959 (2002)
Shin HS, Yang HJ, Kim SB, Lee MS, J. Colloid Interface Sci., 274(1), 89 (2004)
Lee CJ, Kim HJ, Karim MR, Lee MS, Bulletin of the Korean Chemical Society., 27, 545 (2006)
Millo D, Ranieri A, Koot W, Gooijer C, van der Zwan G, Analytical Chemistry., 78, 5622 (2006)
Ozoemena KI, Nyokong T, Electrochim. Acta, 51(13), 2669 (2006)
Jensen RA, Sherin J, Emory SR, Applied Spectroscopy., 61, 832 (2007)
Absalan G, Mehrdjardi MA, Sep. Purif. Technol., 33(1), 95 (2003)
Ulman A, Chem. Rev., 96(4), 1533 (1996)
Schneider TW, Buttry DA, J. Am. Chem. Soc., 115(26), 12391 (1993)
Wingrove AS, Caret RL, Organic Chemistry, Harper & Row Publishers, London, 185 (1981)
Kim MS, Kim MK, Lee CJ, Jung YM, Lee MS, Bulletin of the Korean Chemical Society., 30, 121 (2009)
Suber L, Sondi I, Matijevic E, Goia DV, J. Colloid Interface Sci., 288(2), 489 (2005)
Hu J, Zhao B, Xu W, Li B, Fan Y, Spectrochimica Acta., 58A, 2827 (2002)
Zhang ZJ, Imae T, Sato H, Watanabe A, Ozaki Y, Langmuir, 17(15), 4564 (2001)
Creighton JA, Surface Science., 124, 209 (1983)
Moskovits M, Suh JS, Journal of the American Chemical Society., 108, 4711 (1986)
Kanayama N, Kanbara T, Kitano H, J. Phys. Chem. B, 104(2), 271 (2000)

[Referenced By]

[1] Jeanmaire DL, Van Duyne PR, Journal of Electroanalytical Chemistry., 84, 1 (1977)

[2] Albrecht MG, Creighton JA, Journal of the American Chemical Society., 99, 5215 (1977)

[3] Van Duyne PR, in: Moore CB (Ed.),, Chemical and Biochemical Applications of Lasers, vol. IV, Academic Press, New York, 101 (1979)

[4] Furtak TE, in: Chang RK (Ed.), Surface Enhanced Raman Scattering, Plenum Press, New York, 45 (1982)

[5] Moskovits M, Reviews of Modern Physics., 57, 783 (1985)

[6] Fleischmann M, Hendra DJ, McQuillan AJ, Chemical Physics Letters., 26, 163 (1974)

[7] Saito Y, Wang JJ, Smith DA, Batchelder DN, Langmuir, 18(8), 2959 (2002)

[8] Shin HS, Yang HJ, Kim SB, Lee MS, J. Colloid Interface Sci., 274(1), 89 (2004)

[9] Lee CJ, Kim HJ, Karim MR, Lee MS, Bulletin of the Korean Chemical Society., 27, 545 (2006)

[10] Millo D, Ranieri A, Koot W, Gooijer C, van der Zwan G, Analytical Chemistry., 78, 5622 (2006)

[11] Ozoemena KI, Nyokong T, Electrochim. Acta, 51(13), 2669 (2006)

[12] Jensen RA, Sherin J, Emory SR, Applied Spectroscopy., 61, 832 (2007)

[13] Absalan G, Mehrdjardi MA, Sep. Purif. Technol., 33(1), 95 (2003)

[14] Ulman A, Chem. Rev., 96(4), 1533 (1996)

[15] Schneider TW, Buttry DA, J. Am. Chem. Soc., 115(26), 12391 (1993)

[16] Wingrove AS, Caret RL, Organic Chemistry, Harper & Row Publishers, London, 185 (1981)

[17] Kim MS, Kim MK, Lee CJ, Jung YM, Lee MS, Bulletin of the Korean Chemical Society., 30, 121 (2009)

[18] Suber L, Sondi I, Matijevic E, Goia DV, J. Colloid Interface Sci., 288(2), 489 (2005)

[19] Hu J, Zhao B, Xu W, Li B, Fan Y, Spectrochimica Acta., 58A, 2827 (2002)

[20] Zhang ZJ, Imae T, Sato H, Watanabe A, Ozaki Y, Langmuir, 17(15), 4564 (2001)

[21] Creighton JA, Surface Science., 124, 209 (1983)

[22] Moskovits M, Suh JS, Journal of the American Chemical Society., 108, 4711 (1986)

[23] Kanayama N, Kanbara T, Kitano H, J. Phys. Chem. B, 104(2), 271 (2000)