Preparation, characterization and scale performance of scale inhibitor copolymer modification with chitosan

Xiaorui Guo; Fengxian Qiu; Ke Dong; Xin Zhou; Jing Qi; Yang Zhou; Dongya Yang

Journal of Industrial and Engineering Chemistry, Vol.18, No.6, 2177-2183, November, 2012

DOI10.1016/j.jiec.2012.06.015 Export Citation

Preparation, characterization and scale performance of scale inhibitor copolymer modification with chitosan

Xiaorui Guo, Fengxian Qiu^†, Ke Dong, Xin Zhou, Jing Qi, Yang Zhou, and Dongya Yang

School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China

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A scale inhibitor copolymer modification with chitosan was prepared from maleic anhydride, styrene sulfonic sodium, acrylic amide and chitosan. The conditions of preparing scale inhibitor were optimized. The chemical structure and thermal property were investigated. Using the static experiment method, the influences of copolymer concentration, temperature time, Ca2+ concentration, HCO3- concentration of the system on the inhibition efficiency were investigated. The experimental results showed that the polymer was excellent calcium carbonate scale inhibition and the resistance rate of calcium carbonate scale up to 95.62%, and could be used in the system of high temperature and high hardness water.

Keywords:Copolymer;Chitosan;Scale inhibitor;Inhibition efficiency;Static scale inhibition

[References]

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Gu X, Qiu F, Zhou X, Qi J, Zhou Y, Guo X, Yang D, International Journal of Polymer Analysis and Characterization., 17, 321 (2012)
Demadis KD, Mavredaki E, Stathoulopoulou A, Neofotistou E, Mantzaridis C, Desalination, 213(1-3), 38 (2007)
El Dahan HA, Hegazy HS, Desalination, 127(2), 111 (2000)
Andrei M, Gagliardi F, Journal of Petroleum Science and Engineering., 43, 35 (2004)
Lisitsin D, Yang Q, Hasson D, Semiat R, Desalination., 186, 289 (2005)
Darton EG, Desalination, 132(1-3), 121 (2000)
Senthilmurugan B, Ghosh B, Kundu SS, Haroun M, Kameshwari B, Journal of Petroleum Science and Engineering., 75, 189 (2010)
Segal E, Pan H, Benayoun L, Kopecˇkova´ P, Shaked Y, Kopecˇek J, Satchi-Fainaro R, Biomaterials., 32, 4450 (2011)
Senthilmurugan B, Ghosh B, Sanker S, J. Ind. Eng. Chem., 17(3), 415 (2011)
Wang C, Li SP, Li TD, Desalination, 249(1), 1 (2009)
Singh J, Dutta PK, Dutta J, Hunt AJ, Macquarrie DJ, Clark JH, Carbohydrate Polymers., 76, 188 (2009)
Duan W, Chen C, Jiang L, Li GH, Carbohydrate Polymers., 73, 582 (2008)
Li HS, Liu W, Qi XJ, Desalination, 214(1-3), 193 (2007)
Han H, Gu X, Li D, Zhu MB, Computer Society., 162, 1073 (2011)
Tantayakom V, Sreethawong T, Fogler HS, de Moraes FF, Chavadej S, J. Colloid Interface Sci., 284(1), 57 (2005)
Tang YM, Yang WZ, Yin XS, Liu Y, Yin PW, Wang JT, Desalination, 228(1-3), 55 (2008)

[Referenced By]

[1] Suharso, Buhani, Bahri S, Endaryanto T, Desalination, 265(1-3), 102 (2011)

[2] Gu X, Qiu F, Zhou X, Qi J, Zhou Y, Guo X, Yang D, International Journal of Polymer Analysis and Characterization., 17, 321 (2012)

[3] Demadis KD, Mavredaki E, Stathoulopoulou A, Neofotistou E, Mantzaridis C, Desalination, 213(1-3), 38 (2007)

[4] El Dahan HA, Hegazy HS, Desalination, 127(2), 111 (2000)

[5] Andrei M, Gagliardi F, Journal of Petroleum Science and Engineering., 43, 35 (2004)

[6] Lisitsin D, Yang Q, Hasson D, Semiat R, Desalination., 186, 289 (2005)

[7] Darton EG, Desalination, 132(1-3), 121 (2000)

[8] Senthilmurugan B, Ghosh B, Kundu SS, Haroun M, Kameshwari B, Journal of Petroleum Science and Engineering., 75, 189 (2010)

[9] Segal E, Pan H, Benayoun L, Kopecˇkova´ P, Shaked Y, Kopecˇek J, Satchi-Fainaro R, Biomaterials., 32, 4450 (2011)

[10] Senthilmurugan B, Ghosh B, Sanker S, J. Ind. Eng. Chem., 17(3), 415 (2011)

[11] Wang C, Li SP, Li TD, Desalination, 249(1), 1 (2009)

[12] Singh J, Dutta PK, Dutta J, Hunt AJ, Macquarrie DJ, Clark JH, Carbohydrate Polymers., 76, 188 (2009)

[13] Duan W, Chen C, Jiang L, Li GH, Carbohydrate Polymers., 73, 582 (2008)

[14] Li HS, Liu W, Qi XJ, Desalination, 214(1-3), 193 (2007)

[15] Han H, Gu X, Li D, Zhu MB, Computer Society., 162, 1073 (2011)

[16] Tantayakom V, Sreethawong T, Fogler HS, de Moraes FF, Chavadej S, J. Colloid Interface Sci., 284(1), 57 (2005)

[17] Tang YM, Yang WZ, Yin XS, Liu Y, Yin PW, Wang JT, Desalination, 228(1-3), 55 (2008)