화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Applied Chemistry for Engineering, Vol.23, No.6, 567-571, December, 2012
Export Citation
무기 안료에 의한 전통회화의 변색 연구
A Study on Discoloration of Traditional Paintings by an Inorganic Pigment
김동원, 곽삼탁, 서용수1, 김일규2, 문명준†
  • 부경대학교 공업화학과
  • 1부경대학교 환경연구소
  • 2부경대학교 환경공학과
Dong Won Kim, Sam Tak Kwak, Yong Soo Seo1, Il Kyu Kim2, and Myung Jun Moon†
  • Department of Industrial Chemistry, Pukyong National University, Busan 608-739, Korea
  • 1Environmental Research Center, Pukyong National University, Busan 608-739, Korea
  • 2Department of Environmental Engineering, Pukyong National University, Busan 608-739, Korea
E-mail:
초록
전통회화의 변색은 온도, 습도, 빛, 그리고 대기 오염에 의한 각종 화학 물질들과 사용된 무기 안료와의 화학반응에 의해 일어나기도 한다. 본 연구에서는 조선종이라고 불리는 한지에 석록, 석청 무기 안료를 사용해 전통방법으로 시험편을 제작하고, 인위적인 노화시험을 통해 안료와 환경 요인의 상호 작용에 의한 노화과정을 조사하였다. 석청은 XRD 및 TGA 결과로부터 내후성 시험의 습기와 내염수 시험의 염무에 의해 영향을 받는 것을 알 수 있었다. 하지만 석록은 내후성 시험이나 내자외선 시험 중 주로 자외선에 의해 화학적 변화가 일어나는 것을 색차 및 TGA 결과로부터 볼 수 있었다.
The discoloration of traditional paintings could be induced by various chemical reactions of inorganic pigments due to temperature, humidity, light and air pollution. In this study, we made artificial samples including azurite and malachite as inorganic pigments using the traditional method on hanji called ‘Korean paper’and investigated the artificial aging process occurred by the interaction between pigments and environmental factors. It was found that the azurite was influenced by the humidity of weathering tests and the salt fog of salt spray tests according to XRD and TGA results. However, it was shown that the malachite was chemically changed by the ultraviolet radiation of weathering tests and UV radiation tests according to color difference and TGA results.
Keywords:malachite;azurite;traditional painting;discoloration;inorganic pigment
  1. Han MS, Hong JO, Conservation studies., 24, 132 (2000)
  2. Cheon JH, Kim SH, Conservation Science in Museum., 3, 21 (2001)
  3. Kim JS, Conservation and Restoration of Cultural assets, BKworld, 52 (2001)
  4. Enguita O, Calderon T, Fernandez-Jimenez MT, Beneitez P, Millan A, Garcia G, Nucl. Instrum. Meth. B., 219, 53 (2004)
  5. Frost RL, Ding Z, Kloprogge JT, Martens WN, Thermochim. Acta, 390(1-2), 133 (2002)
  6. Odlyha M, Cohen NS, Foster GM, West RH, Thermochim. Acta, 365(1-2), 53 (2000)
  7. Odlyha M, Cohen NS, Foster GM, Thermochim. Acta, 365(1-2), 35 (2000)
  8. Bicchieri M, Nardone M, Russo PA, Sodo S, Corsi M, Cristoforetti G, Palleschi V, Salvetti A, Tognoni E, Spectrochim. Acta B., 56, 915 (2001)
  9. Hong JO, Jung KY, Conservation studies., 13, 73 (1992)
  10. Cho NC, Hong JO, Moon WS, Hwang JJ, Conservation studies., 21, 119 (2000)
  11. Moon HS, Hwang JJ, Cho NC, Hong JU, Gang DI, Lee MH, NajuBogam-ri 3HoBun, National Research Institute of Cultural Heritage, 77 (2001)
  12. Moon HS, Hwang JJ, Gang DI, Lee MH, Seosamreung Teasil, National Research Institute of Cultural Heritage, 400 (1999)
  13. Moon HS, Cho NC, Hong JU, Hwang JJ, Experimental study on Muryangsujeon of Buseoksa Temple, 380 (2002)
  14. Color name and Hue of Korea traditional standard, National Museum of Contemporary Art, 36 (1991)
  15. Method for specification of color differences for opaque materials, KSA 0063, KSA (Korean Standard Associaiton) (2006)
  16. Hatakeyama T, Zhenhai L, Handbook of Thermal Analysis, John Wiley & Sons Ltd, West Sussex PO19 1UD (1999)