화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.19, No.1, 234-239, January, 2013
DOI10.1016/j.jiec.2012.08.007  Export Citation
Preparation of Ni0.1Mg0.9O nanocrystalline powder and its catalytic performance in methane reforming with carbon dioxide
Rasoul Zanganeh1, Mehran Rezaei1, 2, †, Akbar Zamaniyan3, and Hamid Reza Bozorgzadeh3
  • 1Catalyst and Advanced Materials Research Laboratory, Chemical Engineering Department, Faculty of Engineering, University of Kashan, Kashan, Iran
  • 2Institute of Nanoscience and Nanotechnology, University of Kashan, Kashan, Iran
  • 3Gas Research Division, Research Institute of Petroleum Industry (RIPI) of National Iranian Oil Company, P.O. Box 14665-137, Tehran, Iran
E-mail:
Ni0.1Mg0.9O nanocrystalline powders were prepared by surfactant assisted precipitation method and employed as catalyst in dry reforming. The powders were characterized by using XRD, BET, SEM, TGA/DSC and TPR techniques. The results showed that the surfactant to metal mole ratio affects the textural properties. Increasing in surfactant to metal mole ratio increased the specific surface area and decreased the crystallite and particle size. The Ni0.1Mg0.9O with the highest surface area (115.39 m2 g^(-1)) was employed as catalyst in dry reforming. This catalyst showed a high catalytic activity and stability during 122 h time on stream without any decrease in methane conversion.
Keywords:Dry reforming;Solid solution;Nickel catalyst;Syngas
  1. Xu DY, Li WZ, Ge QJ, Xu HY, Fuel Process. Technol., 86(9), 995 (2005)
  2. Juan-Juan J, Roman-Martinez MC, Illan-Gomez MJ, Applied Catalysis A., 359, 27 (2009)
  3. Zheng B, Jianhua Y, Xiaodong L, Yong C, Kefa C, International Journal of Hydrogen Energy., 33, 5545 (2008)
  4. Luna AEC, Iriarte ME, Appl. Catal. A: Gen., 343(1-2), 10 (2008)
  5. Safariamin M, Tidahy LH, Abi-Aad E, Siffert S, Aboukais A, Comptes Rendus Chimie., 12, 748 (2009)
  6. Therdthianwong S, Therdthianwong A, Siangchin C, Yongprapat S, International Journal of Hydrogen Energy., 33, 991 (2008)
  7. Rivas ME, Fierro JLG, Goldwasser MR, Pietri E, Perez-Zurita MJ, Griboval-Constant A, Leclercq G, Appl. Catal. A: Gen., 344(1-2), 10 (2008)
  8. Hu YH, Catal. Today, 148(3-4), 206 (2009)
  9. Pichas C, Pomonis P, Petrakis D, Ladavos A, Appl. Catal. A: Gen., 386(1-2), 116 (2010)
  10. Gadalla AM, Bower B, Chemical Engineering Science., 43, 3049 (1988)
  11. Reitmeier RE, Atwood K, Bennet HA, Baugh HM, Industrial and Engineering Chemistry Research., 40, 620 (1948)
  12. Ruckenstein E, Hu YH, Appl. Catal. A: Gen., 133(1), 149 (1995)
  13. Hu YH, Ruckenstein E, Catal. Rev.-Sci. Eng., 44(3), 423 (2002)
  14. Tomishige K, Himeno Y, Matsuo Y, Yoshinaga Y, Fujimoto K, Ind. Eng. Chem. Res., 39(6), 1891 (2000)
  15. Ruckenstein E, Wang HY, J. Catal., 205(2), 289 (2002)
  16. Wang YH, Liu HM, Xu BQ, J. Mol. Catal. A-Chem., 299(1-2), 44 (2009)
  17. Djaidja A, Libs S, Kiennemann A, Barama A, Catal. Today, 113(3-4), 194 (2006)
  18. Song CS, Wei P, Catal. Today, 98(4), 463 (2004)
  19. Tomishige K, Catal. Today, 89(4), 405 (2004)
  20. Mondal KC, Choudhary VR, Joshi UA, Appl. Catal. A: Gen., 316(1), 47 (2007)
  21. Parmalina A, Arena F, Frusteri F, Giordano N, Faraday Transactions., 86, 2663 (1990)
  22. Zecchina A, Spoto G, Coluccia S, et al., Faraday Transactions., 80, 1891 (1984)
  23. Rostrup-Nielsen JR, Journal of Catalysis., 27, 343 (1972)
  24. Grenga HE, Lawless KR, Journal of Applied Physics., 43, 1508 (1972)
  25. Rostrup-Nielsen JR, Sehested J, Norskov JK, Advances in Catalysis., 47, 65 (2002)
  26. Tomishige K, Matsuo Y, Yoshinaga Y, Sekine Y, Asadullah M, Fujimoto K, Appl. Catal. A: Gen., 223(1-2), 225 (2002)
  27. Zhang ZL, Verykios XE, Catalysis Today., 21, 589 (1994)
  28. Horiuchi T, Sakuma K, Fukui T, Kubo Y, Osaki T, Mori T, Appl. Catal. A: Gen., 144(1-2), 111 (1996)
  29. Kim GJ, Cho DS, Kim KH, Kim JH, Catal. Lett., 28(1), 41 (1994)
  30. Tang S, Lin J, Tan KL, Catal. Lett., 51(3-4), 169 (1998)