Inorganic Chemistry, Vol.51, No.19, 10068-10070, 2012
Synthesis of a (FeSH)-S-II Complex Stabilized by an Intramolecular N-H center dot center dot center dot S Hydrogen Bond, Which Acts as a H2S Donor
Through use of the reversible protonation of an iron(II) complex containing a deprotonated carboxamido moiety, we prepared and fully characterized the first hydrogen(sulfido)iron(II) complex stabilized by an intramolecular hydrogen bond, which acts as a H2S donor in solution.