화학공학소재연구정보센터
Langmuir, Vol.28, No.47, 16430-16435, 2012
Preparation and Characterization of Conducting Mixed-Valence 9,9'-Dimethyl-3,3'-bicarbazyl Rectangular Nanowires
The facile synthesis of an organic electric conducting nanowire is described. The simple oxidation of 9-methylcarbazole by iron(III) perchlorate in a methanol/acetonitrile mixture under atmospheric pressure and temperature produces abundant nanowires without using a template. The nanowire consists of 9,9'-dimethyl-3,3'-dicarbazyl and has a rectangular nanowire shape with an average diameter of 397 +/- 50 nm and length of 17 +/- 5 mu m. The results of the elemental analysis, H-1 NMR, FT-IR, XPS, and ESR measurements revealed that the chemical composition of the nanowire is (dicarbazyl)(0.12)(dicarbazylium center dot ClO4-)(0.88)center dot H2O. This result, combined with the UV-vis-NIR measurement, demonstrates that 9,9'-dimethyl-3,3'-dicarbazyl stacks in a mixed valence state. The nanowire is electroactive and has an electric conductivity of 3.0 X 10(-5) S cm(-1).