We have shown that the addition of resorcinol di(phenyl phosphate) (RDP)-coated starch can improve the compatibility to either Ecoflex or poly(lactic acid) (PLA). The increased compatibilization enhanced the tensile properties such as yield strength and impact toughness. In particular, we examined the effect of addition of RDP-coated starch on thermal responses of a blend of Ecoflex/PLA. We found that the combination of RDP-coated starches with nanoclays could render the blends self-extinguishing since they are formed as a shell-like chars on the exposure surface against heat, which can prevent the melt polymers against dripping. With an examination on the scanning transmission X-ray microscopy (STXM) images of the blends, the Ecoflex domains were well dispersed in the PIA matrix, while the domains became smaller when the RDP-coated starch was added. Moreover, we demonstrated that the introduction of either flat-like or tube-like clays could provide an increase of interfacial area on the RDP-coated starch surfaces, where each polymer chain preferentially segregates to either the starch or the clay surface. Thus, large complex in-situ grafts with polymers can be formed at the interfaces. Additionally, the complex in-situ grafts could influence flammability of the blends. We have shown that the addition of RDP-coated clays can decrease the mass loss rate of Ecoflex/Starch blends, while a lot of nanofiber are formed on the chars surface, which are entangled each other with the clay platelets. The mechanical properties of the chars structures were examined by nano-indentation, where a good elastic chars formation could keep the internal pressures built up with decomposed gases from melt polymers as well as ductility of the chars could play an important role on releasing the internal gases through small vents on its surface, steadily where a good elastic and ductile chars formation could require keeping the internal pressures built up with decomposed gases from melt polymers. (c) 2012 Elsevier Ltd. All rights reserved.