Bubble-point measurement for the CO2+diethylene glycol diacrylate and CO2+diethylene glycol dimethacrylate systems at high pressure

Sang-Ha Cho; Soon-Do Yoon; Hun-Soo Byun

Korean Journal of Chemical Engineering, Vol.30, No.3, 739-745, March, 2013

DOI10.1007/s11814-012-0196-8 Export Citation

Bubble-point measurement for the CO2+diethylene glycol diacrylate and CO2+diethylene glycol dimethacrylate systems at high pressure

Sang-Ha Cho, Soon-Do Yoon, and Hun-Soo Byun^†

Department of Chemical and Biomolecular Engineering, Chonnam National University, Yeosu, Jeonnam 550-749, Korea

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Pressure-composition isotherms are measured by using a static apparatus for the phase behavior data for the CO2+diethylene glycol diacrylate (DEGDA) and CO2+diethylene glycol dimethacrylate (DEGDMA) systems. The experiments are performed at five temperatures of (313.2 to 393.2) K and pressures up to 28.3 MPa. The solubility of CO2 for the two systems decreases as the temperature increases at a fixed pressure. The CO2+DEGDA and CO2+ DEGDMA systems exhibit type-I phase behavior. The experimental results for the CO2+DEGDA and CO2+DEGDMA systems are correlated with Peng-Robinson equation of state using a mixing rule.

Keywords:Carbon Dioxide;Diethylene Glycol Diacrylate;Diethylene Glycol Dimethacrylate;Peng-Robinson EOS;Phase Behavior

[References]

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McHugh MA, Krukonis VJ, Supercritical Fluid Extraction: Principles and Practice, Second Ed., Stoneham/Butterworth, MA (1994)
Kim SH, Jang YS, Byun HS, Korean J. Chem. Eng., 27(4), 1291 (2010)
Jang YS, Kim SH, Yoo KP, Byun HS, Fluid Phase Equilib., 302(1-2), 234 (2011)
Cho DW, Shin J, Bae W, Kim H, Lee JH, Shin MS, FluidPhase Equilib., 319, 37 (2012)
Peng D, Robinson DB, Ind. Eng. Chem. Fundam., 15, 59 (1976)
Poling BE, Prausnitz JM, O’Connell JP, The properties of liquids and gases, fifth Ed., McGraw-Hill, New York (2001)
Byun HS, Shin JS, J. Chem. Eng. Data, 48(1), 97 (2003)
Jang YS, Yang DS, Byun HS, J. Chem. Eng. Data, 56(11), 4116 (2011)
Kim SH, Jang YS, Yoon SD, Byun HS, Fluid Phase Equilib., 312, 93 (2011)
Kuester JK, Mize JH, Optimization techniques with fortran, McGraw-Hill, New York (1973)
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Chirico RD, Frenkel M, Diky VV, Marsh KN, Wilhoit RC, J. Chem. Eng. Data, 48(5), 1344 (2003)

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[1] http://unionpigment.en.alibaba.com/product/447645230-212322207/DIETHYLENE_GLYCOL_ DIMETHACRYLATE_DEGDMA_.html.

[2] http://chemicalland21.com/industrialchem/functional%20Monomer/DIETHYLENE%20 GLYCOL%20DIMETHACRYLATE.html.

[3] Beckman EJ, J. Supercrit. Fluids, 28(2-3), 121 (2004)

[4] Kendall JL, Canelas DA, Young JL, DeSimone JM, Chem. Rev., 99(2), 543 (1999)

[5] Cooper AI, J. Mater. Chem., 10, 207 (2000)

[6] McHugh MA, Krukonis VJ, Supercritical Fluid Extraction: Principles and Practice, Second Ed., Stoneham/Butterworth, MA (1994)

[7] Kim SH, Jang YS, Byun HS, Korean J. Chem. Eng., 27(4), 1291 (2010)

[8] Jang YS, Kim SH, Yoo KP, Byun HS, Fluid Phase Equilib., 302(1-2), 234 (2011)

[9] Cho DW, Shin J, Bae W, Kim H, Lee JH, Shin MS, FluidPhase Equilib., 319, 37 (2012)

[10] Peng D, Robinson DB, Ind. Eng. Chem. Fundam., 15, 59 (1976)

[11] Poling BE, Prausnitz JM, O’Connell JP, The properties of liquids and gases, fifth Ed., McGraw-Hill, New York (2001)

[12] Byun HS, Shin JS, J. Chem. Eng. Data, 48(1), 97 (2003)

[13] Jang YS, Yang DS, Byun HS, J. Chem. Eng. Data, 56(11), 4116 (2011)

[14] Kim SH, Jang YS, Yoon SD, Byun HS, Fluid Phase Equilib., 312, 93 (2011)

[15] Kuester JK, Mize JH, Optimization techniques with fortran, McGraw-Hill, New York (1973)

[16] http://www.lookchem.com/cas-407/4074-88-8.html.

[17] http://www.lookchem.com/cas-235/2358-84-1.html.

[18] Chirico RD, Frenkel M, Diky VV, Marsh KN, Wilhoit RC, J. Chem. Eng. Data, 48(5), 1344 (2003)