화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.19, No.2, 458-468, March, 2013
DOI10.1016/j.jiec.2012.08.028  Export Citation
Physico-chemical and catalytic properties of Mg-Al hydrotalcite and Mg-Al mixed oxide supported copper catalysts
Manish Dixit, Manish Mishra†, P.A. Joshi, and D.O. Shah
  • Department of Chemical Engineering and Shah-Schulman Center for Surface Science and Nanotechnology, Faculty of Technology, Dharmsinh Desai University, College Road, Nadiad 387 001, Gujarat, India
E-mail:
The Mg-Al hydrotalcite (HT) and Mg-Al mixed oxide supported copper catalysts containing 3-3.5 wt.% copper in finely dispersed form were synthesized and characterized. The effect of support nature on physico-chemical and catalytic properties of supported copper species were studied. The loading of copper on the supports was observed to be influencing the surface acidic, basic and reducibility properties, and catalytic behavior in dehydrogenation of benzyl alcohol. The high basicity and intercalated copper ions in Mg-Al hydrotalcite supported copper sample showed multifunctional activity in catalytic transformations of alcohols (primary, secondary and aromatic alcohols).
Keywords:Hydrotalcites;Alcohols;Dehydrogenation;Transfer hydrogenation;Hydrogen auto transfer
  1. Kaneda K, Mitsudome T, Mizugaki T, Jitsukawa K, Molecules., 15, 8988 (2010)
  2. Perez Y, Ballesteros R, Fajardo M, Sierra I, del Hierro I, Journal of Molecular Catalysis A: Chemical., 352, 45 (2012)
  3. Chary KVR, Seela KK, Naresh D, Ramakanth P, Catalysis Communications., 9, 75 (2008)
  4. Romero A, Santos A, Escrig D, Simon E, Appl. Catal. A: Gen., 392(1-2), 19 (2011)
  5. Hari Prasad Reddy K, Rahul R, Sree Vardhan Reddy S, David Raju B, Rama KS, Catalysis Communications., 10, 879 (2009)
  6. Mikami Y, Ebata K, Mitsudome T, Mizugaki T, Jitsukawa K, Kaneda K, Heterocycles., 80, 855 (2010)
  7. Sh Ri, Wang F, Mu X, Li Y, Huang X, Shen W, Catalysis Communications., 11, 306 (2009)
  8. Shi R, Wang F, Mu X, Ta N, Li Y, Huang X, Shen W, Chinese Journal of Catalysis., 31, 626 (2010)
  9. Bart JCJ, Sneeden RPA, Catalysis Today., 2, 1 (1987)
  10. Chinchen GC, Denny PJ, Jennings JR, Spencer MS, Waugh KC, Applied Catalysis., 36, 1 (1981)
  11. Klier K, Advances in Catalysis., 31, 243 (1982)
  12. Rao RS, Baker RTK, Vannice MA, Catal. Lett., 60(1-2), 51 (1999)
  13. Cesar DV, Perez CA, Salim VMM, Schmal M, AAPG Bull., 176, 205 (1999)
  14. Ji D, Zhu W, Wang Z, Wang G, Catalysis Communications., 8, 1891 (2007)
  15. Fridman VZ, Davydov AA, J. Catal., 195(1), 20 (2000)
  16. Siva Kumar V, Sreevardhan Reddy S, Padmasri AH, David Raju B, Ajitkumar Reddy I, Rama Rao KS, Catalysis Communications., 8, 899 (2007)
  17. Nagaraja BM, Kumar VS, Shashikala V, Padmasri AH, Reddy SS, Raju BD, Rao KSR, J. Mol. Catal. A-Chem., 223(1-2), 339 (2004)
  18. Nagaraja BM, Padmasri AH, Seetharamulu P, Reddy KHP, Raju BD, Rao KSR, J. Mol. Catal. A-Chem., 278(1-2), 29 (2007)
  19. Xiaoding X, Doesburg GBM, Scholten JJF, Catalysis Today., 2, 125 (1987)
  20. Campos-Martin JM, Guerrero-Ruiz A, Fierro JLG, Journal of Catalysis., 156, 209 (1995)
  21. Nikiforova NV, Zhavnerko KA, Petroleum Chemistry URSS., 14, 25 (1974)
  22. Garcia-Ochoa F, Santos A, Industrial and Engineering Chemistry Research., 32, 2626 (1993)
  23. Mendes FM, Schmal M, Appl. Catal. A: Gen., 163(1-2), 153 (1997)
  24. Bautista FM, Campelo JM, Garcia A, Luna D, Marinas JM, Quiros RA, Romero AA, Appl. Catal. A: Gen., 243(1), 93 (2003)
  25. Sagar GV, Rao PVR, Srikanth CS, Chary KVR, J. Phys. Chem. B, 110(28), 13881 (2006)
  26. Nagaraja BM, Siva Kumar V, Shasikala V, Padmasri AH, Sreedhar B, David Raju B, Rama Rao KS, Catalysis Communications., 4, 287 (2003)
  27. Mitsudome T, Mikami Y, Ebata K, Mizugaki T, Jitsukawa K, Kaneda K, Chemical Communications., 4804 (2008)
  28. Crivello ME, Pe´ rez CF, Mendieta SN, Casuscelli SG, Eimer GA, Elı´as VR, Herrero ER, Catalysis Today., 133-135, 787 (2008)
  29. Tichit D, Ge´ rardin C, Durand R, Coq B, Topics in Catalysis., 39, 89 (2006)
  30. Gandia LM, Montes M, Applied Catalysis A., 101, L1 (1993)
  31. Gandia LM, Montes M, Journal of Molecular Catalysis., 94, 347 (1994)
  32. Lin KH, Ko AN, Appl. Catal. A: Gen., 147(2), L259 (1996)
  33. Melo L, Giannetto G, Cardozo L, Llanos A, Garcia L, Magnoux P, Guisnet M, Alvarez F, Catal. Lett., 60(4), 217 (1999)
  34. Chikan V, Molnar A, Balazsik K, J. Catal., 184(1), 134 (1999)
  35. Yang SM, Wu YM, Appl. Catal. A: Gen., 192(2), 211 (2000)
  36. Chen YZ, Liaw BJ, Tan HR, Shen KL, Appl. Catal. A: Gen., 205(1-2), 61 (2001)
  37. Mattos LV, Noronha FB, Monteiro JLF, J. Catal., 209(1), 166 (2002)
  38. Chen YZ, Hwang CM, Liaw CW, Appl. Catal. A: Gen., 169(2), 207 (1998)
  39. Unnikrishnan R, Narayanan S, Journal of Molecular Catalysis A., 144, 173 (1999)
  40. Das N, Tichit D, Durand R, Graffin P, Coq B, Catal. Lett., 71(3-4), 181 (2001)
  41. Di Cosimo JI, Torres G, Apesteguia CR, J. Catal., 208(1), 114 (2002)
  42. Martinez-Ortiz MD, Tichit D, Gonzalez P, Coq B, J. Mol. Catal. A-Chem., 201(1-2), 199 (2003)
  43. Tichit D, Coq B, Cernaux S, Durand R, Catalysis Today., 75, 19 (2002)
  44. Narayanan S, Unnikrishnan R, Appl. Catal. A: Gen., 145(1-2), 231 (1996)
  45. Cavani F, Trifiro F, Vaccari A, Catalysis Today., 11, 173 (1991)
  46. Rives V, Kannan S, Journal of Materials Chemistry., 10, 489 (2000)
  47. Mora M, Jimenez-Sanchidrian C, Ruiz JR, J. Colloid Interface Sci., 302(2), 568 (2006)
  48. Hernandez-Moreno MJ, Ulibarri MA, Rendon JL, Serna CJ, Physics and Chemistry of Minerals., 12, 34 (1985)
  49. Kruissink EC, van Reijden LJ, Ross JRH, Journal of the Chemical Society, Faraday Transactions., 1 77, 649 (1981)
  50. Labajos FM, Rives V, Ulibarri MA, Journal of Materials Science., 27, 1546 (1992)
  51. Rives-Arnau V, Munuera G, Criado JM, Spectroscopy Letters., 12, 733 (1979)
  52. Nakamoto K, Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th ed., J. Wiley & Sons, New York (1986)
  53. Romero MD, Calles JA, Ocana MA, Gomez JM, Microporous and Mesoporous Materials., 111, 243 (2008)
  54. Rynkowski JM, Paryjczak T, Lenik M, Applied Catalysis A: General., 106, 73 (1993)
  55. Di Cosimo JI, Diez VK, Xu M, Iglesia E, Apesteguia CR, J. Catal., 178(2), 499 (1998)
  56. Jyothi TM, Raja T, Sreekumar K, Talawar MB, Rao BS, J. Mol. Catal. A-Chem., 157(1-2), 193 (2000)
  57. Rao KK, Gravelle M, Valente JS, Figueras F, J. Catal., 173(1), 115 (1998)
  58. Agrell J, Birgersson H, Boutonnet M, Melian-Cabrera I, Navarro RM, Fierro JLG, J. Catal., 219(2), 389 (2003)
  59. Mori N, Togo H, Tetrahedron., 61, 5915 (2005)
  60. Marki BE, Scheidt KA, Organic Letters., 10, 4331 (2008)
  61. De Sarkar S, Grimme S, Studer A, J. Am. Chem. Soc., 132(4), 1190 (2010)
  62. Yang J, Zheng HY, Zhu YL, Zhao GW, Zhang CH, Teng BT, Xiang HW, Li Y, Catalysis Communications., 5, 505 (2004)