Methanation of carbon dioxide over mesoporous Ni-Fe-Ru-Al2O3 xerogel catalysts: Effect of ruthenium content

Sunhwan Hwang; Joongwon Lee; Ung Gi Hong; Joon Hyun Baik; Dong Jun Koh; Hyojun Lim; In Kyu Song

Journal of Industrial and Engineering Chemistry, Vol.19, No.2, 698-703, March, 2013

DOI10.1016/j.jiec.2012.10.007 Export Citation

Methanation of carbon dioxide over mesoporous Ni-Fe-Ru-Al2O3 xerogel catalysts: Effect of ruthenium content

Sunhwan Hwang, Joongwon Lee, Ung Gi Hong, Joon Hyun Baik¹, Dong Jun Koh¹, Hyojun Lim², and In Kyu Song^†

School of Chemical and Biological Engineering, Institute of Chemical Processes, Seoul National University, Shinlim-dong, Kwanak-ku, Seoul 151-744, South Korea
¹Environment Research Department, Research Institute of Industrial Science & Technology, Pohang 790-330, South Korea
²POSCO, Gangnam-gu, Seoul 135-389, South Korea

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Mesoporous nickel (35 wt%)-iron (5 wt%)-ruthenium (x wt%)-alumina xerogel (denoted as 35Ni5Fex-RuAX) catalysts with different ruthenium contents (x = 0, 0.2, 0.4, 0.6, 0.8, and 1.0) were prepared by a single-step sol-gel method for use in the methane production from CO2 and H2. Conversion of CO2, yield for CH4, metal surface area, and the amount of desorbed carbon dioxide of the catalysts showed volcanoshaped trends with respect to ruthenium content. Experimental results revealed that metal surface area and the amount of desorbed carbon dioxide of 35Ni5FexRu catalysts were well correlated with conversion of CO2 and yield for CH4.

Keywords:Carbon dioxide methanation;Carbon dioxide;Hydrogen;Mesoporous nickel-iron-ruthenium-alumina xerogel catalyst;Single-step sol-gel method

[References]

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Ocampo F, Louis B, Kiwi-Minsker L, Roger AC, Appl. Catal. A: Gen., 392(1-2), 36 (2011)
Hwang S, Hong UG, Lee J, Baik JH, Koh DJ, Lim H, Song IK, Catal. Lett., 142(7), 860 (2012)
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Chicinas I, Pop V, Isnard O, Breton JML, Juraszek J, Journal of Alloys and Compounds., 352, 34 (2003)
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[2] Kopyscinski J, Schildhauer TJ, Biollaz SMA, Fuel., 89, 1763 (2009)

[3] Wenzhi Z, Hongjun W, Kai Q, Petroleum Exploration and Development., 36, 280 (2009)

[4] Panagiotopoulou P, Kondarides DI, Verykios XE, Appl. Catal. A: Gen., 344(1-2), 45 (2008)

[5] Pan ZY, Dong MH, Meng XK, Zhang XX, Mu XH, Zong BN, Chem. Eng. Sci., 62(10), 2712 (2007)

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[9] Aaron D, Tsouris C, Sep. Sci. Technol., 40(1-3), 321 (2005)

[10] Wang W, Wang S, Ma X, Gong J, Chemical Society Reviews., 40, 3703 (2008)

[11] Krylov OV, Mamedov AK, Russian Chemical Reviews., 64, 877 (1995)

[12] Kowalczyk Z, Stolecki K, Rarog-Pilecka W, Miskiewicz E, Wilczkowska E, Karpiniski Z, Appl. Catal. A: Gen., 342(1-2), 35 (2008)

[13] Ocampo F, Louis B, Kiwi-Minsker L, Roger AC, Appl. Catal. A: Gen., 392(1-2), 36 (2011)

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[15] Bakar WAWA, Ali R, ToemenInui S, Science Iran., 19, 525 (2012)

[16] Ott GL, Fleisch T, Delgass WN, Journal of Catalysis., 60, 394 (1979)

[17] Berry FJ, Liwu L, Chengyu W, Renyuan T, Su Z, Dongbai L, Journal of the Chemical Society, Faraday Transactions., 81, 2293 (1985)

[18] Hwang SH, Lee J, Hong UG, Seo JG, Jung JC, Koh DJ, Lim H, Byun C, Song IK, J. Ind. Eng. Chem., 17(1), 154 (2011)

[19] Seo JG, Youn MH, Nam I, Hwang S, Chung JS, Song IK, Catal. Lett., 130(3-4), 410 (2009)

[20] Zhao D, Luo F, Zhou W, Zhu D, Surface and Coatings Technology., 205, 4254 (2011)

[21] Seo JG, Youn MH, Lee HI, Kim JJ, Yang E, Chung JS, Kim P, Song IK, Chem. Eng. J., 141(1-3), 298 (2008)

[22] Huang L, Xie J, Chen R, Chu D, Chu W, Hsu AT, International Journal of Hydrogen Energy., 33, 7448 (2008)

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[24] Foelske A, Hahn BM, Ko¨ tz R, Electrochemical and Solid-State Letters., 9, A267 (2006)

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[26] Chicinas I, Pop V, Isnard O, Breton JML, Juraszek J, Journal of Alloys and Compounds., 352, 34 (2003)

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[28] Komvokis VG, Marnellos GE, Vasalos IA, Triantafyllidis KS, Appl. Catal. B: Environ., 89(3-4), 627 (2009)

[29] Masalska A, Catalysis Today., 137, 439 (2008)

[30] Liu C, Cundari TR, Wilson AK, Journal of Physical Chemistry C., 116, 5681 (2012)