내구성유연제에 관한 연구(II) -알킬이미다졸린 유도체의 내구성유연제로서의 응용-

김영근; 박홍수; 송갑준

Journal of the Korean Industrial and Engineering Chemistry, Vol.1, No.2, 168-175, December, 1990

Export Citation

내구성유연제에 관한 연구(II) -알킬이미다졸린 유도체의 내구성유연제로서의 응용-

Studies on the Durable Softners (Ⅱ)-Applications of Alkyl Imidazoline Derivatives as the Durable Softners-

김영근, 박홍수, 송갑준

초록

1, 2-Disubstituted imidazoline 화합물인 1-behenoylaminoethyl-1-glycidyl-2-heneicosylimidazolinium chloride(BBIC), 1-behenoylbis(aminoethyl)-1-glycidyl-2-heneicosylimidazolinium chloride(BBIC) 및 1-behenoyltris(aminoethyl)-1-glycidyl-2-heneicosylimidazolinium chloride(BTIC)로부터 유연제 원액인 BHICS, BBICS, BTICS를 각각 제조하여 아크릴섬유에 유연처리를 한 후 유연성, 평활성 및 대전방지성을 측정한 결과 유연제 모두 유연성과 평활성이 양호하였으며 약간의 대전방지성도 보유하였다. 또한 BBICS와 BTICS의 초기강연도는 5grade, 5회 세탁후는 3∼4grade로 각각 나타나 내수성을 지닌 양호한 유연효과를 나타내었다. 아울러 처리온도에 따른 촉감의 내세탁성 및 pH 변화에 따른 촉감의 내세탁성 시험결과 등을 통하여 제조된 유연제가 내구성 유연제임을 입증하였다.

Softners-BHICS, BBICS, and BTICS were prepared from 1, 2-disubstituted imidazoline compounds, such as 1-behenoylaminoethyl-1-glycidyl-2-heneicosylimidazolinium chloride(BHIC), 1-behenoylbis(aminoethyl)-1-glycidyl-2-heneicosylimidazolinium chloride (BBIC), and 1-behenoyltris(aminoethyl)-1-glycidyl-2-heneicosylimidazolinium chloride(BTIC), and treated to acrylic fiber. The measurements of softness, lubricating and antistatic properties showed that they have not only good softness and lubricating property but also a little antistatic property. Furthermore, the initial bending resistance for BBICS and BTICS was 5grade, and remained 3∼4grade after 5 times washing. As results of these tests, they showed good softner effects having durability. The prepared softners were proved to be durable softner through a series of experimental results for washable properties of feeling by varying treating temperature and pH change.

[References]

Kariyone T, "Properties and Applications of Surfactants," 1st ed., p. 120, Saiwai Shobo, Tokyo (1980)
Sakagami S, "Yearbook of Dyeing and Finishing," 1st ed., p. 609, Sen-i Sha, Osaka (1980)
Miyada K, Kako Gijutsu, 21(7), 40 (1986)
Nippon Mektron KK., Jap Kokai 89, 40,677 (1989)
Nippon Mektron KK., Jap Kokai 89, 40,679 (1989)
Nippon Mektron KK., Jap Kokai 89, 40,680 (1989)
Sauer JC, U.S. Patent, 2,268,169 (1941)
Hoechst KK., Brit. Patent, 795,380 (1958)
Hochreuter R, U.S. Patent, 3,793,352 (1974)
Katsumi M, Kawanaka H, U.S. Patent, 3,522,175 (1970)
McConnell RB, U.S. Patent, 3,887,476 (1975)
Park HS, Pyoun MS, Kim YG, J. Korean Ind. Eng. Chem., in press, 2
Minabe Y, Kanebo H, Japan Kokai 70, 12,537 (1970)
Gralen N, Oloffson B, Text. Res. J., 17, 488 (1947)
Hayek M, Am. Dyest. Reptr., 40, 164 (1951)
Wieden H, Noga A, Morzolph H, U.S. Patent, 3,739,054 (1973)
Kindoh IH, "Senshoku Kako Kankei JIS Kigakushu," 3rd ed., pp. 402 ~ 403, Sen-i Kenkyu Co., Tokyo (1972)
Roder HL, J. Text. Inst., 44, T247 (1953)
Simpon BG, Am. Dyest. Reptr., 46, 991 (1957)
Bacon OC, Smith JE, Hughes LE, Am. Dyest. Reptr., 47, 259 (1958)
Mark HF, Bikales NM, Overberger CG, Menges G, Kroschwitz JI, "Encyclopedia of Polymer Science and Engineering," 2nd ed., pp. 335-341, John Wiley & Sons, Inc., New York (1985)
Onuma IZ, Aku KH, "Shinpen Sensyoku," 1st ed., pp. 184 ~ 186, Tokyo Denki Daigaku, Tokyo (1969)
Umeyama H, Morokuma K, J. Am. Chem. Soc., 99(1), 316 (1977)

[Referenced By]

[1] Kariyone T, "Properties and Applications of Surfactants," 1st ed., p. 120, Saiwai Shobo, Tokyo (1980)

[2] Sakagami S, "Yearbook of Dyeing and Finishing," 1st ed., p. 609, Sen-i Sha, Osaka (1980)

[3] Miyada K, Kako Gijutsu, 21(7), 40 (1986)

[4] Nippon Mektron KK., Jap Kokai 89, 40,677 (1989)

[5] Nippon Mektron KK., Jap Kokai 89, 40,679 (1989)

[6] Nippon Mektron KK., Jap Kokai 89, 40,680 (1989)

[7] Sauer JC, U.S. Patent, 2,268,169 (1941)

[8] Hoechst KK., Brit. Patent, 795,380 (1958)

[9] Hochreuter R, U.S. Patent, 3,793,352 (1974)

[10] Katsumi M, Kawanaka H, U.S. Patent, 3,522,175 (1970)

[11] McConnell RB, U.S. Patent, 3,887,476 (1975)

[12] Park HS, Pyoun MS, Kim YG, J. Korean Ind. Eng. Chem., in press, 2

[13] Minabe Y, Kanebo H, Japan Kokai 70, 12,537 (1970)

[14] Gralen N, Oloffson B, Text. Res. J., 17, 488 (1947)

[15] Hayek M, Am. Dyest. Reptr., 40, 164 (1951)

[16] Wieden H, Noga A, Morzolph H, U.S. Patent, 3,739,054 (1973)

[17] Kindoh IH, "Senshoku Kako Kankei JIS Kigakushu," 3rd ed., pp. 402 ~ 403, Sen-i Kenkyu Co., Tokyo (1972)

[18] Roder HL, J. Text. Inst., 44, T247 (1953)

[19] Simpon BG, Am. Dyest. Reptr., 46, 991 (1957)

[20] Bacon OC, Smith JE, Hughes LE, Am. Dyest. Reptr., 47, 259 (1958)

[21] Mark HF, Bikales NM, Overberger CG, Menges G, Kroschwitz JI, "Encyclopedia of Polymer Science and Engineering," 2nd ed., pp. 335-341, John Wiley & Sons, Inc., New York (1985)

[22] Onuma IZ, Aku KH, "Shinpen Sensyoku," 1st ed., pp. 184 ~ 186, Tokyo Denki Daigaku, Tokyo (1969)

[23] Umeyama H, Morokuma K, J. Am. Chem. Soc., 99(1), 316 (1977)