고체초강산 촉매와 그 응용

손종락

Journal of the Korean Industrial and Engineering Chemistry, Vol.3, No.1, 7-17, March, 1992

Export Citation

고체초강산 촉매와 그 응용

Solid Superacid Catalyst and Its Application

손종락

초록

100% H₂SO₄ (H₀=-11.93)보다 더 강한 산을 초강산이라고 한다. 그러나 고체초강산 촉매는 액체초강산촉매에 비하여 촉매와 반응생성물의 분리의 용이성, 촉매의 반복사용가능, 촉매의 재생가능 등과 같은 많은 이점을 가지고 있다. 이 총설에서는 고체초강산 촉매의 종류, 제법, 그리고 화학반응에서의 응용에 대하여 소개한다.

The acid stronger than H₀= -11.93, which corresponds to the acid strength of 100% H₂SO₄, is known as superacid. However, solid superacid catalysts have many advantages such as an easy separation of products from catalyst, the repeated uses and regeneration of catalysts, as compared with liquid superacids. In this paper, the kinds of solid superacids, the preparation methods, and their applications for chemical reactions are introduced.

[References]

Gillespie RJ, Accounts Chem. Res., 1, 202 (1968)
Kobayashi S, Danda H, Saegusa T, Bull. Chem. Soc. Jpn., 46, 3214 (1973)
Hull NF, Conant JB, J. Am. Chem. Soc., 49, 3047 (1927)
Olah GA, Halprn Y, Shen J, Mo YK, J. Am. Chem. Soc., 95, 4960 (1973)
Commeyras A, Olah GA, J. Am. Chem. Soc., 91, 2929 (1969)
Olah GA, Prakash GKS, Sommer J, Science, 206, 13 (1979)
Hammett LP, Deyrup AJ, J. Am. Chem. Soc., 54, 2721 (1932)
Hattori H, Takahashi O, Takagi M, Tanabe K, J. Catal., 68, 132 (1981)
Tanabe K, Hattori H, Chem. Lett., 625 (1976)
Kelly JT, Sechrist CN, U.S. Patent, 3,248,343, April 26 (1966)
Olah GA, Messina G, U.S. Patent, 3,993,587, Nov. 23 (1976)
Hammer GP, Mattox WJ, U.S. Patent, 3,961,036, June 1 (1976)
Herbstman S, Webb AN, Estes JH, U.S. Patent, 4,113,657, Sept 12 (1978)
Drago RS, Getty EE, J. Am. Chem. Soc., 110, 3311 (1988)
Getty EE, Drago RS, Inorg. Chem., 29, 1186 (1990)
Drago RS, Getty EE, U.S. Patent, 4,719,190, Jan 12 (1988)
Hino M, Arata K, Chem. Lett., 477 (1979)
Hino M, Arata K, Chem. Lett., 1259 (1979)
Hino M, Arata K, J. Chem. Soc.-Chem. Commun., 1148 (1979)
Hino M, Kobayashi S, Arata K, J. Am. Chem. Soc., 101, 6439 (1979)
Hino M, Arata K, J. Chem. Soc.-Chem. Commun., 851 (1980)
Sohn JR, Kim HW, J. Mol. Catal., 52, 361 (1989)
Sohn JR, Kim HJ, J. Catal., 42, 428 (1986)
Arata K, Hino M, 表面, 19, 75 (1981)
Yamaguchi T, Jin T, Tanabe K, J. Phys. Chem., 90, 3148 (1986)
Matsucashi H, Hino M, Arata K, Chem. Lett., 1027 (1988)
Sohn JR, Jang HJ, J. Mol. Catal., 64, 349 (1991)
Sohn JR, Kim HW, Kim JT, HWAHAK KONGHAK, 24(6), 521 (1986)
Arata K, Hino M, Proceed. 9th Int. Cong. Catal. P, 1727, Calgary, Canada (1988)
Hino M, Arata K, J. Chem. Soc.-Chem. Commun., 1259 (1988)
Hino M, Arata K, Chem. Lett., 971 (1989)
Sohn JR, Kim HW, Kim JT, J. Mol. Catal., 41, 375 (1987)
Sohn JR, Kim HJ, Bull. Korean Chem. Soc., 6, 248 (1985)
Sohn JR, Jang HJ, Kim HW, Korean J. Chem. Eng., 7(1), 7 (1990)
Ono Y, Yamaguchi K, Kitajima N, J. Catal., 64, 13 (1980)
Ono Y, Tanabe T, Kitajima N, J. Catal., 56, 47 (1979)
Ono Y, Tanabe T, Kitajima N, Chem. Lett., 625 (1978)
Ono Y, Sakuma S, Tanabe T, Kitajima N, Chem. Lett., 1061 (1978)
Tanabe K, Kayo A, Yamaguchi T, J. Chem. Soc.-Chem. Commun., 602 (1981)
Itoh M, Morishige K, Hattori H, "Preparation of Catalysts," B. Delmon, P.A. Jacobs, G. Poncelat, Elsevier, Amsterdam, p. 65 (1976)
Hino M, Arata K, J. Chem. Soc.-Chem. Commun., 1148 (1979)
Tanabe K, In Heterogeneous Catalysis; Shapiro, B.L. Ed., Texas A & M University Press; College Station, TX, Vol. 2, pp. 71-94 (1984)
Ayame A, Izumizawa T, J. Chem. Soc.-Chem. Commun., 645 (1989)
Stocker M, J. Mol. Catal., 29, 371 (1985)
Rajadhyaksha RA, Chaudhari DD, Ind. Eng. Chem. Res., 26, 1743 (1987)
Hino M, Arata K, Chem. Lett., 963 (1980)
Sohn JR, Jang HJ, J. Mol. Catal., submitted for publication
Sohn JR, Jang HJ, J. Catal., 132, 563 (1991)
Sohn JR, Jang HJ, J. Catal., in press (1992)
Nagase Y, Jin T, Hattori H, Yamaguchi T, Tanabe K, Bull. Chem. Soc. Jpn., 58, 916 (1985)
Hino M, Arata K, Chem. Lett., 20, 1483 (1985)
Yamamoto M, Yoshida T, Kotanigawa T, J. Chem. Soc. Jpn., 5, 838 (1985)
Scurrel MS, Appl. Catal., 34, 109 (1987)
Tanaka T, Itagaki A, Zhang G, Hattori H, Tanabe K, J. Catal., 122, 384 (1990)

[1] Gillespie RJ, Accounts Chem. Res., 1, 202 (1968)

[2] Kobayashi S, Danda H, Saegusa T, Bull. Chem. Soc. Jpn., 46, 3214 (1973)

[3] Hull NF, Conant JB, J. Am. Chem. Soc., 49, 3047 (1927)

[4] Olah GA, Halprn Y, Shen J, Mo YK, J. Am. Chem. Soc., 95, 4960 (1973)

[5] Commeyras A, Olah GA, J. Am. Chem. Soc., 91, 2929 (1969)

[6] Olah GA, Prakash GKS, Sommer J, Science, 206, 13 (1979)

[7] Hammett LP, Deyrup AJ, J. Am. Chem. Soc., 54, 2721 (1932)

[8] Hattori H, Takahashi O, Takagi M, Tanabe K, J. Catal., 68, 132 (1981)

[9] Tanabe K, Hattori H, Chem. Lett., 625 (1976)

[10] Kelly JT, Sechrist CN, U.S. Patent, 3,248,343, April 26 (1966)

[11] Olah GA, Messina G, U.S. Patent, 3,993,587, Nov. 23 (1976)

[12] Hammer GP, Mattox WJ, U.S. Patent, 3,961,036, June 1 (1976)

[13] Herbstman S, Webb AN, Estes JH, U.S. Patent, 4,113,657, Sept 12 (1978)

[14] Drago RS, Getty EE, J. Am. Chem. Soc., 110, 3311 (1988)

[15] Getty EE, Drago RS, Inorg. Chem., 29, 1186 (1990)

[16] Drago RS, Getty EE, U.S. Patent, 4,719,190, Jan 12 (1988)

[17] Hino M, Arata K, Chem. Lett., 477 (1979)

[18] Hino M, Arata K, Chem. Lett., 1259 (1979)

[19] Hino M, Arata K, J. Chem. Soc.-Chem. Commun., 1148 (1979)

[20] Hino M, Kobayashi S, Arata K, J. Am. Chem. Soc., 101, 6439 (1979)

[21] Hino M, Arata K, J. Chem. Soc.-Chem. Commun., 851 (1980)

[22] Sohn JR, Kim HW, J. Mol. Catal., 52, 361 (1989)

[23] Sohn JR, Kim HJ, J. Catal., 42, 428 (1986)

[24] Arata K, Hino M, 表面, 19, 75 (1981)

[25] Yamaguchi T, Jin T, Tanabe K, J. Phys. Chem., 90, 3148 (1986)

[26] Matsucashi H, Hino M, Arata K, Chem. Lett., 1027 (1988)

[27] Sohn JR, Jang HJ, J. Mol. Catal., 64, 349 (1991)

[28] Sohn JR, Kim HW, Kim JT, HWAHAK KONGHAK, 24(6), 521 (1986)

[29] Arata K, Hino M, Proceed. 9th Int. Cong. Catal. P, 1727, Calgary, Canada (1988)

[30] Hino M, Arata K, J. Chem. Soc.-Chem. Commun., 1259 (1988)

[31] Hino M, Arata K, Chem. Lett., 971 (1989)

[32] Sohn JR, Kim HW, Kim JT, J. Mol. Catal., 41, 375 (1987)

[33] Sohn JR, Kim HJ, Bull. Korean Chem. Soc., 6, 248 (1985)

[34] Sohn JR, Jang HJ, Kim HW, Korean J. Chem. Eng., 7(1), 7 (1990)

[35] Ono Y, Yamaguchi K, Kitajima N, J. Catal., 64, 13 (1980)

[36] Ono Y, Tanabe T, Kitajima N, J. Catal., 56, 47 (1979)

[37] Ono Y, Tanabe T, Kitajima N, Chem. Lett., 625 (1978)

[38] Ono Y, Sakuma S, Tanabe T, Kitajima N, Chem. Lett., 1061 (1978)

[39] Tanabe K, Kayo A, Yamaguchi T, J. Chem. Soc.-Chem. Commun., 602 (1981)

[40] Itoh M, Morishige K, Hattori H, "Preparation of Catalysts," B. Delmon, P.A. Jacobs, G. Poncelat, Elsevier, Amsterdam, p. 65 (1976)

[41] Hino M, Arata K, J. Chem. Soc.-Chem. Commun., 1148 (1979)

[42] Tanabe K, In Heterogeneous Catalysis; Shapiro, B.L. Ed., Texas A & M University Press; College Station, TX, Vol. 2, pp. 71-94 (1984)

[43] Ayame A, Izumizawa T, J. Chem. Soc.-Chem. Commun., 645 (1989)

[44] Stocker M, J. Mol. Catal., 29, 371 (1985)

[45] Rajadhyaksha RA, Chaudhari DD, Ind. Eng. Chem. Res., 26, 1743 (1987)

[46] Hino M, Arata K, Chem. Lett., 963 (1980)

[47] Sohn JR, Jang HJ, J. Mol. Catal., submitted for publication

[48] Sohn JR, Jang HJ, J. Catal., 132, 563 (1991)

[49] Sohn JR, Jang HJ, J. Catal., in press (1992)

[50] Nagase Y, Jin T, Hattori H, Yamaguchi T, Tanabe K, Bull. Chem. Soc. Jpn., 58, 916 (1985)

[51] Hino M, Arata K, Chem. Lett., 20, 1483 (1985)

[52] Yamamoto M, Yoshida T, Kotanigawa T, J. Chem. Soc. Jpn., 5, 838 (1985)

[53] Scurrel MS, Appl. Catal., 34, 109 (1987)

[54] Tanaka T, Itagaki A, Zhang G, Hattori H, Tanabe K, J. Catal., 122, 384 (1990)