화학공학소재연구정보센터
Journal of the Korean Industrial and Engineering Chemistry, Vol.3, No.2, 201-206, June, 1992
플라스틱 폐기물의 건류 및 열분해
Gasification and Pyrolysis Technology for the Treatment of Plastics Waste
Annual amount of plastics waste including rubber and leather waste, generated in 1990 was about 2,600,000 tons. Amount of generation of plastics waste has rapidly increased, but fractions of recycling and incineration have gradually decreased. Recently, two-stage incinerator, consisting of gasifier and gas combustor, draws much attention in Korea. Plastics are gasified in the starved air condition in the gasifier and produced gas is fired in the combustor. Combustion of produced gas is much easier than that of solid plastics, and produces a little pollutants. Standardzation of technology and process automation are still needed, but this incineration technology is in the commercial stage. Next topic concerned with this two-stage incineration will be how to treat complex plastics waste including toxic substances generated from automobiles and household appliances. Pyrolysis, realized by indirect heating in inert atmosphere, can provide high-quality products with minimum emissions. Many plastics are easily decomposed into oil in pyrolysis conditions, which can be utilized as chemical feedstocks, or gasoline or kerosene depending on feed materials and operating conditions. This has been demonstrated in several pilot-scale tests performed in Japan, Germany, etc. Easy removal of HCl from PVC is one of the most decisive merits of pyrolysis process. But in general, further efforts should be made for the process to obtain marketability. The future of pyrolysis process depends on public concern about environmental problems and oil prices.
  1. 환경처, "한국환경연감" (1991)
  2. Leidner J, Plastics Waste, Recovery of Economic Value, Marcel Dekker, New York, NY (1981)
  3. 김영성, "폐기물 열분해 반응연구(I)," 대체에너지 기술개발사업 보고서 89D301-103FG, 동력자원부 (1990)
  4. Hilado CJ, Pyrolysis of Polymers, Volume 13 Fire and Flammability Series, Technomic, Westport, CT (1976)
  5. 에너지관리공단, "1990년도 대체에너지 기술개발 사업보고서 초록집" (1991)
  6. Jones J, Chem. Eng., 2, 87 (1978)
  7. 김희상, "폐기물의 건류가스 연료화 기술개발," 한국건류가스산업 연구보고서, 에너지관리공단 (1989)
  8. 김영성, "폐기물 열분해 반응연구(II)," 대체에너지 기술개발사업 보고서 901D104-103FC, 동력자원부 (1991)
  9. 김영성, "폐플라스틱 유동층 열분해 공정개발 연구(I)," 대체에너지 기술개발사업 보고서 911D104-112FGI, 동력자원부 (1992)
  10. Kaminsky W, Frank J, J. Anal. Appl. Pyrolysis, 19, 311 (1991) 
  11. Rrosch U, Kaminsky W, "Investigation of Toxic Component in Products from Municipal Waste-Sewage Sludge Pyrolysis," In Pyrolysis and Gasification, Ferrero, G.L., Maniatis, K., Buekens, A., and Bridgwater, A.V., Elsevier, Essex, England, pp. 473-478 (1989)
  12. Kaminsky W, Makromol. Chem. Macromol. Symp., 48-49, 381 (1991)