화학공학소재연구정보센터
Combustion Science and Technology, Vol.185, No.1, 1-16, 2013
Reaction Characteristics of Methanol Noncatalytic Partial Oxidation Stabilized by Ceramic Honeycomb
A ceramic honeycomb was employed in a 1-kW class compact tubular fuel reformer based on noncatalytic partial oxidation (POX) of methanol. POX was stabilized on the outlet surface of the ceramic honeycomb under various experimental conditions with different equivalence ratios (phi) and thermal loads (qload); the latter represents the thermal input to the reformer calculated from the lower heating value (LHV) of methanol. The best performance of the reformer was achieved at phi=3.5, and the adiabatic flame temperature was achieved. The location where the reaction occurred was determined, and the reaction was found to stabilize at an almost identical location under a wide range of thermal load conditions. This robust feature of the reaction is a significant characteristic of the ceramic honeycomb. By inserting a secondary honeycomb downstream of the reaction region, it was possible to move the reaction region upstream. This shifting of the reaction region was a result of the energy regeneration attributed to the adiabatic features of the honeycomb, and resulted in an improvement in reformer performance.