Different mini emulsion polymerizations were carried out with the combination of different concentration of anionic surfactant such as sodium dodecyl sulfate (SDS) or hydrophobic alkane such as (hexadecane), and/or different monomer ratios. The best comonomers composition that would lead to the best polymer latex properties to obtain nanoscale polymer latexes was studied. The polymer latexes in a size range between 156 and 65 nm by varying the SDS concentrations from 2 to 6 wt % were obtained, and also the particle size of the obtained polymer latexes decreases with the increases of hexadecane (HD) concentrations, and the best result was obtained with 4 wt % of a hexadecane. The best polymer latex properties in terms of particle size and binder softness were found in the best monomer ratio of BA:MMA:MAA (17.5:1.5:1.5) as the solid content was adapted to be 20%. Higher K/S values and improved crocking fastness are obtained with printing pastes containing prepared binder.