Molecular triads based on bis(porphyrin)-anthraquinone having azomethine bridge at the pyrrole-beta position have been designed and synthesized. Both free-base AQ-(H-2)(2) and zinc AQ-(Zn)(2) triads are characterized by elemental analysis, MALDI-MS, H-1 NMR, UV-visible, and fluorescence spectroscopy (steady-state and time-resolved) as well as electrochemical method. The absorption spectra of both Soret and Q-bands of the triads are red-shifted by 12-20 nm with respect to their monomer units. The study supported by theoretical calculations manifests that there exists a negligible electronic communication in the ground state between the donor porphyrin and acceptor anthraquinone of these triads. However, interestingly, both the triads exhibit significant fluorescence emission quenching (51-92%) of the porphyrin emission compared to their monomeric units. The emission quenching is attributed to the excited-state intramolecular photoinduced electron transfer from porphyrins to anthraquinone. The electron-transfer rates (k(ET)) of these triads are found in the range 1.0 x 10(8) to 7.7 x 10(9) s(-1) and are found to be solvent dependent.