화학방법에 의한 액-액 계면 면적

박상욱; 문진복; 신정호; 박대원; 김종현

Journal of the Korean Industrial and Engineering Chemistry, Vol.4, No.1, 103-112, March, 1993

Export Citation

화학방법에 의한 액-액 계면 면적

Effective Interfacial Area in an Agitated Liquid-Liquid Contactor by a Chemical Method

박상욱, 문진복, 신정호, 박대원, 김종현

초록

교반기를 사용하여 n-butyl acetate의 알카리 가수분해반응의 액-액 불균일계에서 n-butyl acetate의 총괄물 질전달속도를 측정하여 실험변수와의 관계를 고찰하고, 화학반응을 수반한 물질전달기구를 경막설에 적용하여 용질에 대한 확산방정식의 근사해로부터 구한 n-butyl acetate의 반응촉진계수의 이론값과 측정값을 비교하여 물질전달계수를 구하였다. 이로부터 분산용액의 액적 면적을 산출할 수 있었다.

The rates of overall mass transfer of n-butyl acetate in the alkaline hydrolysis of n-butyl acetate were measured by using a mechanically agitated vessel in order to get the relationship between the mass transfer rates and experimental variables. The interfacial area between liquid-liquid heterogeneous phases could be obtained by comparing the theoretical values of reaction enhancement factor from an approximated solution of a diffusion equation based on the film theory with the experimental data.

[References]

Gordon KF, Sherwood TK, Chem. Eng. Prog., 50, 15 (1954)
Maroudas NG, Sawistowski H, Chem. Eng. Sci., 19, 919 (1964)
Mayers GRA, Chem. Eng. Sci., 16, 69 (1961)
McManamey WJ, Chem. Eng. Sci., 16, 251 (1961)
McManamey WJ, Davies JT, Woolen JM, Coe JR, Chem. Eng. Sci., 28, 1061 (1973)
McManamey WJ, Multani SKS, Davies JT, Chem. Eng. Sci., 30, 1536 (1975)
Bulicka J, Prochazka J, Chem. Eng. Sci., 31, 137 (1976)
Asai S, Hatanaka J, Auekawa YJ, J. Chem. Eng. Jpn., 16, 463 (1983)
Asai S, Hatanaka J, Kimura T, Yoshizawa H, Ind. Eng. Chem. Res., 26, 483 (1987)
Seo YG, Park SB, Lee WK, Korean J. Chem. Eng., 4(2), 120 (1987)
Park SW, Yang SS, Kim JH, Asai S, HWAHAK KONGHAK, 27(6), 744 (1989)
Lagisetty JS, Das PK, Kumar R, Chem. Eng. Sci., 41, 65 (1986)
Nanda AK, Sharma MM, Chem. Eng. Sci., 21, 707 (1966)
Nanda AK, Sharma MM, Chem. Eng. Sci., 22, 769 (1967)
Sharma MM, Nanda AK, Trans. Inst. Chem. Eng., 46, T44 (1968)
Puranik SA, Sharma MM, Chem. Eng. Sci., 25, 257 (1970)
Cox PR, Strachan AN, Chem. Eng. Sci., 27, 457 (1972)
Rod V, Chem. Eng. J., 7, 137 (1974)
Sada E, Kumazawa H, Butt MA, Can. J. Chem. Eng., 55, 475 (1977)
Grosjean PRL, Sawistowski H, Trans. Inst. Chem. Eng., 58, 59 (1980)
Janakiraman B, Sharma MM, Chem. Eng. Sci., 37, 1497 (1982)
Asai S, Konishi Y, Yamaguchi H, Ind. Eng. Chem. Fundam., 25, 452 (1986)
Morrison RT, Boyd RN, "Organic Chemistry," 4th Ed. 832, Allyn and Bacon, Inc., London (1983)
Danckwrts PV, "Gas-Liquid Reactions," 115, McGraw-Hill Book Co., New York (1970)
vanKrevelen DW, Hoftijzer PJ, Chem. Trans. Chim., 67, 563 (1948)
Hikita H, Asai S, Kagaku Kogaku, 27, 823 (1963)
Hikita H, Ishikawa H, Kagaku Kogaku, 37, 1054 (1973)
Davies JT, "Turbulence Phenomena," 51 Academic Press, New York (1972)
Danckwerts PV, Gillham AJ, Trans. Inst. Chem., 44, T42 (1966)
Hikita H, Asai S, Takatsuka T, Chem. Eng. J., 11, 131 (1976)
Park SW, Moon JB, Ko MS, Kim GW, J. Korean Ind. Eng. Chem., 3(1), 119 (1992)
Ratcliff GA, Holdcroft SG, Trans. Inst. Chem. Eng., 41, 315 (1963)
Wilke CR, Chang P, AIChE J., 1, 264 (1955)
Vinograd JR, Mcbain JW, J. Am. Chem. Soc., 63, 2008 (1941)
Sharma MM, Danckwerts PV, Brit. Chem. Eng., 15, 522 (1970)
Sharma MM, Nanda AK, Trans. Inst. Chem. Eng., 46, T44 (1968)
Sankholkar DS, Sharma MM, Chem. Eng. Sci., 28, 2089 (1973)
Laddha SS, Sharma MM, Chem. Eng. Sci., 31, 843 (1976)

[Referenced By]

[1] Gordon KF, Sherwood TK, Chem. Eng. Prog., 50, 15 (1954)

[2] Maroudas NG, Sawistowski H, Chem. Eng. Sci., 19, 919 (1964)

[3] Mayers GRA, Chem. Eng. Sci., 16, 69 (1961)

[4] McManamey WJ, Chem. Eng. Sci., 16, 251 (1961)

[5] McManamey WJ, Davies JT, Woolen JM, Coe JR, Chem. Eng. Sci., 28, 1061 (1973)

[6] McManamey WJ, Multani SKS, Davies JT, Chem. Eng. Sci., 30, 1536 (1975)

[7] Bulicka J, Prochazka J, Chem. Eng. Sci., 31, 137 (1976)

[8] Asai S, Hatanaka J, Auekawa YJ, J. Chem. Eng. Jpn., 16, 463 (1983)

[9] Asai S, Hatanaka J, Kimura T, Yoshizawa H, Ind. Eng. Chem. Res., 26, 483 (1987)

[10] Seo YG, Park SB, Lee WK, Korean J. Chem. Eng., 4(2), 120 (1987)

[11] Park SW, Yang SS, Kim JH, Asai S, HWAHAK KONGHAK, 27(6), 744 (1989)

[12] Lagisetty JS, Das PK, Kumar R, Chem. Eng. Sci., 41, 65 (1986)

[13] Nanda AK, Sharma MM, Chem. Eng. Sci., 21, 707 (1966)

[14] Nanda AK, Sharma MM, Chem. Eng. Sci., 22, 769 (1967)

[15] Sharma MM, Nanda AK, Trans. Inst. Chem. Eng., 46, T44 (1968)

[16] Puranik SA, Sharma MM, Chem. Eng. Sci., 25, 257 (1970)

[17] Cox PR, Strachan AN, Chem. Eng. Sci., 27, 457 (1972)

[18] Rod V, Chem. Eng. J., 7, 137 (1974)

[19] Sada E, Kumazawa H, Butt MA, Can. J. Chem. Eng., 55, 475 (1977)

[20] Grosjean PRL, Sawistowski H, Trans. Inst. Chem. Eng., 58, 59 (1980)

[21] Janakiraman B, Sharma MM, Chem. Eng. Sci., 37, 1497 (1982)

[22] Asai S, Konishi Y, Yamaguchi H, Ind. Eng. Chem. Fundam., 25, 452 (1986)

[23] Morrison RT, Boyd RN, "Organic Chemistry," 4th Ed. 832, Allyn and Bacon, Inc., London (1983)

[24] Danckwrts PV, "Gas-Liquid Reactions," 115, McGraw-Hill Book Co., New York (1970)

[25] vanKrevelen DW, Hoftijzer PJ, Chem. Trans. Chim., 67, 563 (1948)

[26] Hikita H, Asai S, Kagaku Kogaku, 27, 823 (1963)

[27] Hikita H, Ishikawa H, Kagaku Kogaku, 37, 1054 (1973)

[28] Davies JT, "Turbulence Phenomena," 51 Academic Press, New York (1972)

[29] Danckwerts PV, Gillham AJ, Trans. Inst. Chem., 44, T42 (1966)

[30] Hikita H, Asai S, Takatsuka T, Chem. Eng. J., 11, 131 (1976)

[31] Park SW, Moon JB, Ko MS, Kim GW, J. Korean Ind. Eng. Chem., 3(1), 119 (1992)

[32] Ratcliff GA, Holdcroft SG, Trans. Inst. Chem. Eng., 41, 315 (1963)

[33] Wilke CR, Chang P, AIChE J., 1, 264 (1955)

[34] Vinograd JR, Mcbain JW, J. Am. Chem. Soc., 63, 2008 (1941)

[35] Sharma MM, Danckwerts PV, Brit. Chem. Eng., 15, 522 (1970)

[36] Sharma MM, Nanda AK, Trans. Inst. Chem. Eng., 46, T44 (1968)

[37] Sankholkar DS, Sharma MM, Chem. Eng. Sci., 28, 2089 (1973)

[38] Laddha SS, Sharma MM, Chem. Eng. Sci., 31, 843 (1976)