Boron nitride nanotubes (BNNT) synthesized by a ball milling-annealing were surface-modified using three different types of polymeric materials. Those materials were chosen depending on future applications especially in polymer nanocomposite fabrications. We found that the surface-modified BNNT can be purified with a simple dilution-centrifugation step, which would be suitable for large-scale purification. Degree of purification was monitored by means of the center peak position and FWHM of E-2g mode of BNNT in Raman spectra. As the purification of BNNT develops, the peak position was upshifted while FWHM of the peak was narrowed. (c) 2012 Elsevier Ltd. All rights reserved.