Development of microwave induced hydrodesulfurization of petroleum streams: A review

Hui Shang; Wei Du; Zhichang Liu; Haichao Zhang

Journal of Industrial and Engineering Chemistry, Vol.19, No.4, 1061-1068, July, 2013

DOI10.1016/j.jiec.2012.12.044 Export Citation

Development of microwave induced hydrodesulfurization of petroleum streams: A review

Hui Shang^†, Wei Du, Zhichang Liu^†, and Haichao Zhang

State Key Laboratory of Heavy Oil Processing, China University of Petroleum (Beijing), Changping District, Beijing 102249, PR China

E-mail:,

This paper provides a general overview of microwave applications in hydrodesulfurization (HDS) of various petroleum streams. Deep desulfurization is required for petroleum streams due to stringent sulfur specifications to meet environmental norms. The progress achieved during recent years in catalyst-based HDS technologies is illustrated by using microwaves due to its unique selective and volumetric heating capacity. Based on literature reports, it may be concluded that microwave assisted desulfurization of petroleum streams can be successfully performed under less severe conditions, with significant advantages. This is expected to result in savings in utilities, catalyst consumption, eventually leading to increased fuel yields.

Keywords:Microwave energy;Hydrodesulfurization;Catalyst;Petroleum

[References]

Speight JG, The Desulfurization of Heavy Oils and Residua, CRC Press, New York (1999)
Hatanaka S, Yamada M, Sadakane O, Ind. Eng. Chem. Res., 36(5), 1519 (1997)
Cheng WC, Kim G, Peters AW, Zhao X, Rajagopalan K, Ziebarth MS, Pereira CJ, Catal. Rev.-Sci. Eng., 40(1-2), 39 (1998)
Leflaive P, Lemberton JL, Perot G, Mirgain C, Carriat JY, Colin JM, Studies in Surface Science and Catalysis., 130, 2465 (2000)
Song CS, Catal. Today, 86(1-4), 211 (2003)
Meredith R, Engineers Handbook of Industrial Microwave Heating, Institute of Electrical Engineers, London (1998)
Stuerga D, Gaillard P, Lallemant M, Tetrahedron., 52, 5505 (1996)
Bram G, Loupy A, Majdoub M, Gutierrez E, Ruiz-Hitzsky E, Tetrahedron., 46, 5167 (1990)
Inoue K, Method employing wave energy for the extraction of sulfur from petroleum and the like, US 3616375 (1971)
Panchenkov GM, Erchenkov VV, Chemistry and Technology of Fuels and Oils., 16, 433 (1980)
Ashton SL, Cutmore NG, Rooch GJ, Watt JS, Zastawny HW, McEwan AJ, SPE Paper No. 28814, Melbourne, Australia (1994)
Kirkbride CG, Sulfur removal from crude petroleum, US 4234402 (1978)
Loupy A, Microwaves in Organic Synthesis, second ed., WILEY-VCH Verlag GmbH & Co kGaA, Weinheim (2006)
Perry WL, Datye AK, Prinja AK, Brown LF, Katz JD, AIChE J., 48(4), 820 (2002)
Zhang X, Hayward DO, Inorganic Chimica Acta., 359, 3421 (2006)
Khan RM, Al-Shafel Emad N, Microwave-promoted desulfurization of crude oil, WO 2009/064501 (2009)
Miadonye A, Snow S, Irwin DJG, Rashid Khan M, WIT Transactions on Engineering Sciences., Computational methods in multiphase flow V, 63, 455 (2009)
Clark DE, West DC. Folz JK, Materials Science and Engineering A., 287, 153 (2000)
Beijing Zhongjun Tianwei Ltd., Dielectric Constants of Common Materials, 2010, available from: http://www.twell.cn/Picture/DownLoad/200801201043363104 26.pdf(cited September, 2012).
Zhang XL, Hayward DO, Mingos DMP, Catal. Lett., 84(3-4), 225 (2002)
Mutyala S, Fairbridge C, Pare JRJ, Belanger JMR, Ng S, Hawkins R, Fuel Process. Technol., 91(2), 127 (2010)
Zhang Z, Chauhan H, Hutcheon RM, The microwave response of mixtures of of Canadian bitumen fractions, University of Ottawa (2010)
Borges J, Silva AM, Aguiar AP, Borges LEP, Carlos J, Santos A, Dias MHC, Journal of Molecular Structure: THEOCHEM., 822, 80 (2007)
Chianelli RR, Pecorano TA, Halbert TR, Pan WH, Stiefel EJ, Journal of Catalysis., 86, 226 (1984)
Zhang XL, Hayward DO, Mingos DMP, Catal. Lett., 88(1-2), 33 (2003)
Zhang XL, Hayward DO, Lee C, Mingos DMP, Appl. Catal. B: Environ., 33(2), 137 (2001)
Jackson C, Soveran D, Desulfurization of crude oils using microwave energy, P-110-300-C-95 (1995)
Ovalles C, Morales F, Rivas LA, Urbano N, Microwave heated catalyst and process, US 6171479 (2001)
Ovalles C, Morales F, Rivas LA, Urbano N, Microwave heated catalyst and process, US 6017845 (2000)
Shang H, Zhang H, Li W, Liu Z, Bai BLZ, Journal of KunMing University of Science and Technology (Natural Science Edition)., 37, 294 (2012)
Leadbeater NE, Khan MR, Energy Fuels, 22(3), 1836 (2008)
Purta DA, Portnoff MA, Pourarian F, Nasta MA, Zhang J, Catalyst for the treatment of organic compounds, US 2004077485 (2004)
Wan JKS, Kriz JF, Hydrodesulphurization of hydro cracked pitch, US Patent 4545879 (1985)
Mills P, Korlann S, Bussell ME, Reynolds MA, Ovchinnikov MV, Angelici RJ, Stinner C, Weber T, Prins R, J. Phys. Chem. A, 105(18), 4418 (2001)
Wiegand BC, Friend CM, Chemical Reviews., 92, 491 (1992)
Orita H, Uchida K, Itoh N, J. Mol. Catal. A-Chem., 193(1-2), 197 (2003)
Cristol S, Paul JF, Schovsbo C, Veilly E, Payen E, J. Catal., 239(1), 145 (2006)
Raybaud P, Hafner J, Kresse G, Toulhoat H, Physical Review Letters., 80, 1481 (1998)
Gomez RAM, Treatment of crude oils, US 6955753 (2005)

[Referenced By]

[1] Speight JG, The Desulfurization of Heavy Oils and Residua, CRC Press, New York (1999)

[2] Hatanaka S, Yamada M, Sadakane O, Ind. Eng. Chem. Res., 36(5), 1519 (1997)

[3] Cheng WC, Kim G, Peters AW, Zhao X, Rajagopalan K, Ziebarth MS, Pereira CJ, Catal. Rev.-Sci. Eng., 40(1-2), 39 (1998)

[4] Leflaive P, Lemberton JL, Perot G, Mirgain C, Carriat JY, Colin JM, Studies in Surface Science and Catalysis., 130, 2465 (2000)

[5] Song CS, Catal. Today, 86(1-4), 211 (2003)

[6] Meredith R, Engineers Handbook of Industrial Microwave Heating, Institute of Electrical Engineers, London (1998)

[7] Stuerga D, Gaillard P, Lallemant M, Tetrahedron., 52, 5505 (1996)

[8] Bram G, Loupy A, Majdoub M, Gutierrez E, Ruiz-Hitzsky E, Tetrahedron., 46, 5167 (1990)

[9] Inoue K, Method employing wave energy for the extraction of sulfur from petroleum and the like, US 3616375 (1971)

[10] Panchenkov GM, Erchenkov VV, Chemistry and Technology of Fuels and Oils., 16, 433 (1980)

[11] Ashton SL, Cutmore NG, Rooch GJ, Watt JS, Zastawny HW, McEwan AJ, SPE Paper No. 28814, Melbourne, Australia (1994)

[12] Kirkbride CG, Sulfur removal from crude petroleum, US 4234402 (1978)

[13] Loupy A, Microwaves in Organic Synthesis, second ed., WILEY-VCH Verlag GmbH & Co kGaA, Weinheim (2006)

[14] Perry WL, Datye AK, Prinja AK, Brown LF, Katz JD, AIChE J., 48(4), 820 (2002)

[15] Zhang X, Hayward DO, Inorganic Chimica Acta., 359, 3421 (2006)

[16] Khan RM, Al-Shafel Emad N, Microwave-promoted desulfurization of crude oil, WO 2009/064501 (2009)

[17] Miadonye A, Snow S, Irwin DJG, Rashid Khan M, WIT Transactions on Engineering Sciences., Computational methods in multiphase flow V, 63, 455 (2009)

[18] Clark DE, West DC. Folz JK, Materials Science and Engineering A., 287, 153 (2000)

[19] Beijing Zhongjun Tianwei Ltd., Dielectric Constants of Common Materials, 2010, available from: http://www.twell.cn/Picture/DownLoad/200801201043363104 26.pdf(cited September, 2012).

[20] Zhang XL, Hayward DO, Mingos DMP, Catal. Lett., 84(3-4), 225 (2002)

[21] Mutyala S, Fairbridge C, Pare JRJ, Belanger JMR, Ng S, Hawkins R, Fuel Process. Technol., 91(2), 127 (2010)

[22] Zhang Z, Chauhan H, Hutcheon RM, The microwave response of mixtures of of Canadian bitumen fractions, University of Ottawa (2010)

[23] Borges J, Silva AM, Aguiar AP, Borges LEP, Carlos J, Santos A, Dias MHC, Journal of Molecular Structure: THEOCHEM., 822, 80 (2007)

[24] Chianelli RR, Pecorano TA, Halbert TR, Pan WH, Stiefel EJ, Journal of Catalysis., 86, 226 (1984)

[25] Zhang XL, Hayward DO, Mingos DMP, Catal. Lett., 88(1-2), 33 (2003)

[26] Zhang XL, Hayward DO, Lee C, Mingos DMP, Appl. Catal. B: Environ., 33(2), 137 (2001)

[27] Jackson C, Soveran D, Desulfurization of crude oils using microwave energy, P-110-300-C-95 (1995)

[28] Ovalles C, Morales F, Rivas LA, Urbano N, Microwave heated catalyst and process, US 6171479 (2001)

[29] Ovalles C, Morales F, Rivas LA, Urbano N, Microwave heated catalyst and process, US 6017845 (2000)

[30] Shang H, Zhang H, Li W, Liu Z, Bai BLZ, Journal of KunMing University of Science and Technology (Natural Science Edition)., 37, 294 (2012)

[31] Leadbeater NE, Khan MR, Energy Fuels, 22(3), 1836 (2008)

[32] Purta DA, Portnoff MA, Pourarian F, Nasta MA, Zhang J, Catalyst for the treatment of organic compounds, US 2004077485 (2004)

[33] Wan JKS, Kriz JF, Hydrodesulphurization of hydro cracked pitch, US Patent 4545879 (1985)

[34] Mills P, Korlann S, Bussell ME, Reynolds MA, Ovchinnikov MV, Angelici RJ, Stinner C, Weber T, Prins R, J. Phys. Chem. A, 105(18), 4418 (2001)

[35] Wiegand BC, Friend CM, Chemical Reviews., 92, 491 (1992)

[36] Orita H, Uchida K, Itoh N, J. Mol. Catal. A-Chem., 193(1-2), 197 (2003)

[37] Cristol S, Paul JF, Schovsbo C, Veilly E, Payen E, J. Catal., 239(1), 145 (2006)

[38] Raybaud P, Hafner J, Kresse G, Toulhoat H, Physical Review Letters., 80, 1481 (1998)

[39] Gomez RAM, Treatment of crude oils, US 6955753 (2005)