Prediction of solubility parameter from intrinsic viscosity

Kyong Ho Han; Gil Song Jeon; In Kwon Hong; Seung Bum Lee

Journal of Industrial and Engineering Chemistry, Vol.19, No.4, 1130-1136, July, 2013

DOI10.1016/j.jiec.2012.12.009 Export Citation

Prediction of solubility parameter from intrinsic viscosity

Kyong Ho Han, Gil Song Jeon¹, In Kwon Hong¹, and Seung Bum Lee^{1, †}

Department of Electronics and Electrical Engineering, Dankook University, 448-701, Republic of Korea
¹Department of Chemical Engineering, Dankook University, 448-701, Republic of Korea

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Polymer for coating such as epoxy and alkyd resin use additives for enhancing physical properties, hardening acceleration, and decreasing viscosity. Therefore, diluent selection is important for blending of additives in the resin. The choice of these solvents is determined by comparing the solubility parameters. In this study, it is a measure of the intrinsic viscosity of epoxy resin by Ubbelohde viscometer and epoxy resin is calculated solubility parameter through intrinsic viscosity. The epoxy and alkyd resins’ solubility parameters were calculated from their intrinsic viscosities to be epoxy resin (δ2d = 16.55, δ2 p = 5.98, δ2h = 6.53) and alkyd resin (δ2d = 19.11, δ2 p = 3.96, δ2h = 4.86), respectively. Their total solubility parameters were calculated to be epoxy resin (δ2t = 18.77) and alkyd resin (δ2t = 20.11), respectively.

Keywords:Solubility parameter;Intrinsic viscosity;Epoxy resin;Alkyd resin;Chi parameter

[References]

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Bustamante P, Navarro-Lupio´ n J, Escalera B, European Journal of Pharmaceutical Sciences., 24(2), 229 (2005)
Frederic B, Christine C, Eugene EE, International Journal of Polymeric Materials., 57(11), 1036 (2008)
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Kwaambwa HM, Goodwin JW, Hughes RW, Reynolds PA, Colloids and Surfaces A., 294(1), 14 (2007)
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Bozdogan AE, Polymer, 45(18), 6415 (2004)
Park KA, Kim KH, Hong IK, J. Ind. Eng. Chem., 17(2), 213 (2011)
Higiro J, Herald TJ, Alavi S, Food Research International., 39(2), 165 (2006)
Goh KKT, Matia-Merino L, Neil Pinder D, Saavedra C, Singh H, Food Hydrocolloids., 25(3), 286 (2011)
Marcus Y, The Journal of Supercritical Fluids., 62(8), 60 (2012)
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Eslamimanesh A, Esmaeilzadeh F, Fluid Phase Equilib., 291(2), 141 (2010)
Bordes C, Fre´ ville V, Ruffin E, Marote P, Gauvrit JY, Brianc¸on S, Lante´ ri P, International Journal of Pharmaceutics., 383(1-2), 236 (2010)
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O¨ zdemir C, Gu¨ ner A, European Polymer Journal., 43(7), 3068 (2007)
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Adamska K, Voelkel A, Journal of Chromatography A., 1132(1-2), 260 (2006)
Adamska K, Bellinghausen R, Voelkel A, Journal of Chromatography A., 1195(1), 146 (2008)
Adamska K, Voelkel A, International Journal of Pharmaceutics., 304(1-2), 11 (2005)
Morris GA, Castile J, Smith A, Adams GG, Harding SE, Polymer Degradation and Stability., 94(9), 1344 (2009)
Lai SL, Yang DH, Food Hydrocolloids., 21(5), 739 (2007)
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Doyle JP, Lyons G, Edwin R, Food Hydrocolloids., 23(6), 1501 (2009)

[Referenced By]

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[4] Tog˘rul H, Arslan N, Carbohydrate Polymers., 54(1), 63 (2003)

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[11] Marcus Y, The Journal of Supercritical Fluids., 62(8), 60 (2012)

[12] Vay K, Scheler S, Frieß W, International Journal of Pharmaceutics., 416(1), 202 (2011)

[13] Charles M. Hansen, Hansen Solubility Parameters: A User’s Handbook, CRC, Press,New York (2000)

[14] Eslamimanesh A, Esmaeilzadeh F, Fluid Phase Equilib., 291(2), 141 (2010)

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[19] Park KA, Lee HJ, Hong IK, J. Ind. Eng. Chem., 16(3), 490 (2010)

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[23] Morris GA, Castile J, Smith A, Adams GG, Harding SE, Polymer Degradation and Stability., 94(9), 1344 (2009)

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