Poly[1-(N,N-bis-carboxymethyl)amino-3-allylglycerol-co-dimethylacrylamide] brushes grafted onto siliceous support for preconcentration and determination of cobalt (II) in human plasma and environmental samples

Homayon Ahmad Panahi; Mahshid Nikpour Nezhati; Rohollah Abedini Kashkoieh; Elham Moniri; Igor Yu. Galaev

Korean Journal of Chemical Engineering, Vol.30, No.9, 1722-1728, September, 2013

DOI10.1007/s11814-013-0100-1 Export Citation

Poly[1-(N,N-bis-carboxymethyl)amino-3-allylglycerol-co-dimethylacrylamide] brushes grafted onto siliceous support for preconcentration and determination of cobalt (II) in human plasma and environmental samples

Homayon Ahmad Panahi^†, Mahshid Nikpour Nezhati, Rohollah Abedini Kashkoieh, Elham Moniri¹, and Igor Yu. Galaev²

Department of Chemistry, Central Tehran Branch, Islamic Azad University, Shahrak Ghods, Simaye Iran, Tehran, Iran
¹Department of Chemistry, Varamin (Pishva) Branch, Islamic Azad University, Shahrak Naghsh Jahan, Pishva, Iran
²DSM Food Specialties, B.V. Delft The Netherlands

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A chelating matrix prepared by surface grafting of polymer containing a functional monomer, poly[1-(N,Nbis-carboxymethyl)amino-3-allylglycerol-co-methylacrylamide] (poly(AGE/IDA-co-DMAA) onto a modified silica. The silica surface was modified by silylation with 3-mercaptopropyltrimethoxysilane followed by graft polymerization. Monomer of allyl glycidyl ether-iminodiacetic acid was synthesized by reaction of allyl glycidyl ether with iminodiacetic acid. The chelating sorbent can be reused for 15 cycles of sorption-desorption without any significant change in sorption capacity. The profile of cobalt uptake on the sorbent reflects good accessibility of chelating sites in poly(AGE/IDA-co-DMAA)-grafted silica gel. The equilibrium adsorption data of Co(II) on modified sorbent were analyzed by Langmuir, Freundlich, Temkin and Redlich-Peterson models. The method was applied for cobalt ions determination in human plasma and sea water sample with satisfactory results.

Keywords:Solid Phase Extraction;Polymer Grafting;Cobalt;Isotherm Study;Preconcentration

[References]

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Lison D, De Boecka M, Verougstraete V, Occup. Environ.Med., 58(10), 619 (2001)
Yaman M, Curr. Med. Chem., 13(21), 2513 (2006)
International Agency for Research on Cancer (IARC), Monographs on the evaluation of carcinogenic risks to human, Lyon, 52, 363 (1991)
Jiang Z, Yu JC, Liu H, Anal. Sci., 21, 851 (2005)
Sawula GM, Talanta., 64, 80 (2004)
Guo Y, Din B, Liu Y, Talanta., 62, 209 (2004)
Tanaka T, Tanaka Y, Saitoh T, Hiraide M, J. Anal. At Spectrom., 17, 1556 (2002)
Zhang Y, Luo WH, Li H, Spectrosc. Spect. Anal., 25, 576 (2005)
Tuzen M, Soylak M, Elci L, Anal. Chim. Acta., 548(1-2), 101 (2005)
FeizBakhsh A, Ahmad Panahi H, Nikpour Nezhati M, Amrollahi M, Mahmoudi F, Water Environ. Res., 81(5), 532 (2009)
Ahmad Panahi H, Sid Kalal H, Moniri E, Nikpour Nezhati M, Taheri Menderjani M, Ranjbar Kelahrodi S, Mahmoudi F, Microchem. J., 93, 49 (2009)
Hashemi-Moghaddam H, Ahmad Panahi H, Nikpour Nezhati M, Anal. Lett., 42, 1 (2009)
Rodriguez F, Principles of polymer systems, 2nd Ed., McGraw Hill, New York, 93 (1982)
Ivanov AE, Eccles J, Ahmad Panahi H, Kumar A, Kuzimenkova MV, Nilsson L, Bergenstahl B, Long N, Phillips GJ, Mikhalovsky SV, Galaev YI, Mattiasson B, J. Biomed. Mater.Res. Part A., 88(1), 213 (2009)
Jahanshahi M, Ahmad Panahi H, Hajizadeh S, Moniri E, Chromatographia., 68, 41 (2008)
Ivanov AE, Ahmad Panahi H, Kuzimenkova MV, Nilsson L, Bergenstehl B, Waqif Hosain S, Jahanshahi, Galaev IY, Mattiasson B, Chem. Eur. J., 12, 7204 (2006)
Ahmad Panahi H, Morshedian J, Mehmandost N, Moniri E, Galaev IY, J. Chromatogr. A., 1217, 5165 (2010)
Langmuir L, J. Am. Chem. Soc., 40, 1361 (1918)
Hall KL, Eagleton LC, Acrivos A, Vermeulen T, Ind. Eng.Chem. Fundam., 5, 212 (1966)
Freundlich HMA, J. Phys. Chem., 57, 385 (1906)
Ho YS, Ofomaja AE, Biochem. Eng. J., 30, 117 (2006)
Yachenko NAD, Yachenko AK, Sukhan VV, J. Anal.Chem., 57(11), 1022 (2002)
Mu FT, Jia Q, Tian YM, Shang OK, Adsorption., 14, 31 (2008)
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Kumar M, Rathore DPS, Singh AK, Fresenius. J. Anal.Chem., 370, 377 (2001)
Kumar M, Rathore DPS, Singh AK, Mikrochim. Acta., 137, 127 (2001)
Venkatesh G, Singh AK, Talanta., 67, 187 (2005)
Tewari PK, Singh AK, Talanta., 53, 823 (2001)
Sarmani SB, Abdullah MP, Bobaker AM, J. Radioanal.Nucl. Chem., 259(2), 257 (2004)
Kumar M, Rathore DPS, Singh AK, Talanta., 51, 1187 (2000)
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[Referenced By]

[1] Valko M, Rhodes CJ, Moncol J, Chem. Biol. Interact., 160(1), 1 (2006)

[2] Lison D, De Boecka M, Verougstraete V, Occup. Environ.Med., 58(10), 619 (2001)

[3] Yaman M, Curr. Med. Chem., 13(21), 2513 (2006)

[4] International Agency for Research on Cancer (IARC), Monographs on the evaluation of carcinogenic risks to human, Lyon, 52, 363 (1991)

[5] Jiang Z, Yu JC, Liu H, Anal. Sci., 21, 851 (2005)

[6] Sawula GM, Talanta., 64, 80 (2004)

[7] Guo Y, Din B, Liu Y, Talanta., 62, 209 (2004)

[8] Tanaka T, Tanaka Y, Saitoh T, Hiraide M, J. Anal. At Spectrom., 17, 1556 (2002)

[9] Zhang Y, Luo WH, Li H, Spectrosc. Spect. Anal., 25, 576 (2005)

[10] Tuzen M, Soylak M, Elci L, Anal. Chim. Acta., 548(1-2), 101 (2005)

[11] FeizBakhsh A, Ahmad Panahi H, Nikpour Nezhati M, Amrollahi M, Mahmoudi F, Water Environ. Res., 81(5), 532 (2009)

[12] Ahmad Panahi H, Sid Kalal H, Moniri E, Nikpour Nezhati M, Taheri Menderjani M, Ranjbar Kelahrodi S, Mahmoudi F, Microchem. J., 93, 49 (2009)

[13] Hashemi-Moghaddam H, Ahmad Panahi H, Nikpour Nezhati M, Anal. Lett., 42, 1 (2009)

[14] Rodriguez F, Principles of polymer systems, 2nd Ed., McGraw Hill, New York, 93 (1982)

[15] Ivanov AE, Eccles J, Ahmad Panahi H, Kumar A, Kuzimenkova MV, Nilsson L, Bergenstahl B, Long N, Phillips GJ, Mikhalovsky SV, Galaev YI, Mattiasson B, J. Biomed. Mater.Res. Part A., 88(1), 213 (2009)

[16] Jahanshahi M, Ahmad Panahi H, Hajizadeh S, Moniri E, Chromatographia., 68, 41 (2008)

[17] Ivanov AE, Ahmad Panahi H, Kuzimenkova MV, Nilsson L, Bergenstehl B, Waqif Hosain S, Jahanshahi, Galaev IY, Mattiasson B, Chem. Eur. J., 12, 7204 (2006)

[18] Ahmad Panahi H, Morshedian J, Mehmandost N, Moniri E, Galaev IY, J. Chromatogr. A., 1217, 5165 (2010)

[19] Langmuir L, J. Am. Chem. Soc., 40, 1361 (1918)

[20] Hall KL, Eagleton LC, Acrivos A, Vermeulen T, Ind. Eng.Chem. Fundam., 5, 212 (1966)

[21] Freundlich HMA, J. Phys. Chem., 57, 385 (1906)

[22] Ho YS, Ofomaja AE, Biochem. Eng. J., 30, 117 (2006)

[23] Yachenko NAD, Yachenko AK, Sukhan VV, J. Anal.Chem., 57(11), 1022 (2002)

[24] Mu FT, Jia Q, Tian YM, Shang OK, Adsorption., 14, 31 (2008)

[25] Tewari PK, Singh AK, Fresenius. J. Anal. Chem., 367, 562 (2000)

[26] Kumar M, Rathore DPS, Singh AK, Fresenius. J. Anal.Chem., 370, 377 (2001)

[27] Kumar M, Rathore DPS, Singh AK, Mikrochim. Acta., 137, 127 (2001)

[28] Venkatesh G, Singh AK, Talanta., 67, 187 (2005)

[29] Tewari PK, Singh AK, Talanta., 53, 823 (2001)

[30] Sarmani SB, Abdullah MP, Bobaker AM, J. Radioanal.Nucl. Chem., 259(2), 257 (2004)

[31] Kumar M, Rathore DPS, Singh AK, Talanta., 51, 1187 (2000)

[32] Gurnani V, Singh AK, Venkataramani B, Talanta., 61, 889 (2003)