Evaluation of recovery characteristic of acidic and alkaline solutions from NaNO3 using conventional electrodialysis and electrodialysis with bipolar membranes

Kwang-Wook Kim; Jun-Taek Hyun; Keun-Young Lee; Eil-Hee Lee; Dong-Young Chung; Jei-Kwon Moon

Korean Journal of Chemical Engineering, Vol.30, No.9, 1760-1769, September, 2013

DOI10.1007/s11814-013-0089-5 Export Citation

Evaluation of recovery characteristic of acidic and alkaline solutions from NaNO3 using conventional electrodialysis and electrodialysis with bipolar membranes

Kwang-Wook Kim^†, Jun-Taek Hyun¹, Keun-Young Lee, Eil-Hee Lee , Dong-Young Chung, and Jei-Kwon Moon

Korea Atomic Energy Research Institute, 989-111, Daedeok-daero, Yuseong-gu, Daejeon 305-353, Korea
¹Techwin Co., Ltd., 66-26, Songjeong, Heungdeok, Cheongju 361-721, Korea

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We compared the electrodialysis performance for HNO3 and NaOH recovery from NaNO3 solution by conventional electrodialysis (ED) and electrodialysis with bipolar membranes (EDBM) at constant current and constant voltage. The individual resistances of the components of the electrodialysis systems were also evaluated. The electrodialysis extent for HNO3 and NaOH recovery from NaNO3 solution was almost proportional to the total amount of electricity supplied to the system, regardless of the operation mode and the electrodialysis systems. For the same volume of feed solution, the energy consumption and current efficiency differed depending on the operation mode and the electrodialysis system. In both the ED and EDBM systems, the conductivity of the feed solution strongly affected the overall cell resistance after approximately 50% of the ions in the feed solution had migrated.

Keywords:Electrodialysis;Acid;Base;Bipolar Membrane (BM);Cation Exchange Membrane (CEM);Anion Exchange Membrane (AEM)

[References]

Kim KW, Hyun JT, Lee KY, Lee EH, Chung DY, Moon JK, Ind. Eng. Chem. Res., 51(18), 6275 (2012)
International Atomic Energy Agency, IAEA Report, IAEA-TECDOC-1115 (1999)
Kim KW, Hyun JT, Lee EH, Park GI, Lee KW, Yoo MJ, Song KC, Moon JK, J. Nucl. Mater., 418, 93 (2011)
Peper SM, Brodnax LF, Field SE, Zehnder RA, Valdez SN, Runde WH, Ind. Eng. Chem. Res., 43(26), 8188 (2004)
Mason CFV, Turney WRJR, Thomson BM, Lu N, Longmire PA, Chisholm-Brause CJ, Environ. Sci. Technol., 31, 2707 (1997)
Chung DY, Seo HS, Lee JW, Yang HB, Lee EH, Kim KW, J. Radioanal. Nucl. Chem., 284, 123 (2010)
Kim KW, Kim YH, Lee SY, Lee EH, Song KC, Song K, Ind. Eng. Chem. Res., 48(4), 2085 (2009)
Tongwen X, Resour. Conserv. Recycl., 37, 1 (2002)
Wang Y, Zhang N, Huang C, Xu T, J. Membr. Sci., 385-386, 226 (2011)
Cauwenberg V, Peels J, Resbeut S, Pourcelly G, Sep. Purif. Technol., 22-23, 115 (2001)
Fidaleo M, Moresi M, Biotechnol. Bioeng., 91(5), 556 (2005)
Bauer B, Gerner FJ, Strathmann H, Desalination., 68, 279 (1988)
Mani KN, J. Membr. Sci., 58, 117 (1991)
Schaffner F, Pontalier PY, Sanchez V, Lutin F, Desalination, 170(2), 113 (2004)
Tanioka A, Shimizu K, Hosono T, Eto R, Osaki T, Colloids Surf. A: Physicochem. Eng. Aspects., 159, 305 (1999)
Venugopal K, Dharmalingam S, Desalination., 296, 37 (2012)
Sadrzadeh M, Mohammadi T, Desalination, 249(1), 279 (2009)
Sata T, Mine K, Higa M, J. Membr. Sci., 141(1), 137 (1998)

[Related Articles]

[1] Kim KW, Hyun JT, Lee KY, Lee EH, Chung DY, Moon JK, Ind. Eng. Chem. Res., 51(18), 6275 (2012)

[2] International Atomic Energy Agency, IAEA Report, IAEA-TECDOC-1115 (1999)

[3] Kim KW, Hyun JT, Lee EH, Park GI, Lee KW, Yoo MJ, Song KC, Moon JK, J. Nucl. Mater., 418, 93 (2011)

[4] Peper SM, Brodnax LF, Field SE, Zehnder RA, Valdez SN, Runde WH, Ind. Eng. Chem. Res., 43(26), 8188 (2004)

[5] Mason CFV, Turney WRJR, Thomson BM, Lu N, Longmire PA, Chisholm-Brause CJ, Environ. Sci. Technol., 31, 2707 (1997)

[6] Chung DY, Seo HS, Lee JW, Yang HB, Lee EH, Kim KW, J. Radioanal. Nucl. Chem., 284, 123 (2010)

[7] Kim KW, Kim YH, Lee SY, Lee EH, Song KC, Song K, Ind. Eng. Chem. Res., 48(4), 2085 (2009)

[8] Tongwen X, Resour. Conserv. Recycl., 37, 1 (2002)

[9] Wang Y, Zhang N, Huang C, Xu T, J. Membr. Sci., 385-386, 226 (2011)

[10] Cauwenberg V, Peels J, Resbeut S, Pourcelly G, Sep. Purif. Technol., 22-23, 115 (2001)

[11] Fidaleo M, Moresi M, Biotechnol. Bioeng., 91(5), 556 (2005)

[12] Bauer B, Gerner FJ, Strathmann H, Desalination., 68, 279 (1988)

[13] Mani KN, J. Membr. Sci., 58, 117 (1991)

[14] Schaffner F, Pontalier PY, Sanchez V, Lutin F, Desalination, 170(2), 113 (2004)

[15] Tanioka A, Shimizu K, Hosono T, Eto R, Osaki T, Colloids Surf. A: Physicochem. Eng. Aspects., 159, 305 (1999)

[16] Venugopal K, Dharmalingam S, Desalination., 296, 37 (2012)

[17] Sadrzadeh M, Mohammadi T, Desalination, 249(1), 279 (2009)

[18] Sata T, Mine K, Higa M, J. Membr. Sci., 141(1), 137 (1998)