Adsorption thermodynamics and kinetics of disperse dye on poly(p-phenylene benzobisoxazole) fiber pretreated with polyphosphoric acid

Yu Guan; Ya-hong Mao; Dong Wei; Xiu-xing Wang; Pu-xin Zhu

Korean Journal of Chemical Engineering, Vol.30, No.9, 1810-1818, September, 2013

DOI10.1007/s11814-013-0103-y Export Citation

Adsorption thermodynamics and kinetics of disperse dye on poly(p-phenylene benzobisoxazole) fiber pretreated with polyphosphoric acid

Yu Guan^{1, 2}, Ya-hong Mao³, Dong Wei², Xiu-xing Wang⁴, and Pu-xin Zhu^{1, †}

¹Textile Institute, Sichuan University, Chengdu 610065, P. R. China
²Bureau of Quartermaster Military Representation of the General Logistics Department, PLA, Beijing 100071, P. R. China
³Department of Dyeing and Chemistry, Chengdu Textile College, Chengdu 611731, P. R. China
⁴Quartermaster Equipment Institute of General Logistics Department, PLA, Beijing 100010, P. R. China, Korea

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Adsorption thermodynamic and kinetic studies of C. I. disperse dye 60 on PBO fiber pretreated with polyphosphoric acid (PPA) were carried out under the conditions of pH 6.0±0.2, initial dye concentration 0.05-1.0 g/L and liquor ratio 2,000 : 1. The results showed that the equilibrium adsorption isotherm of the disperse dye on the pretreated PBO fiber was a Langmuir-Nernst mixed Model and the saturated adsorption capacity of the turning point was 1.046mg/g. The thermodynamic parameters were calculated by the equilibrium adsorption isotherm, such as standard affinity, enthalpy change and entropy change, which indicated that the adsorption of disperse dye on the pretreated PBO fiber was an exothermic process. Based on the thermodynamic and kinetic data, the adsorption of the dye on the pretreated PBO fiber was a kinetics controlled process, and the disperse dye could only diffuse into the surface layer of pretreated PBO fiber. Meanwhile, the adsorption kinetics of disperse dye on pretreated PBO fiber well agreed with a pseudofirst-order kinetic model.

Keywords:PBO Fiber;Adsorption;Diffusion;Thermodynamics;Kinetics;Disperse Dye

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[Referenced By]

[1] Bourbigot S, Flambard X, Duquesne S, Polym. Int., 50, 157 (2001)

[2] Chae HG, Kumar S, J. Appl. Polym. Sci., 100(1), 791 (2006)

[3] Zhang T, Hu DY, Jin JH, Yang SL, Li G, Jiang JM, Appl. Surf. Sci., 256(7), 2073 (2010)

[4] Feng DD, Wang SF, Zhuang QX, Wu PP, Han ZW, Polymer, 45(26), 8871 (2004)

[5] Song B, Fu Q, Ying LH, Liu XY, Zhuang QX, Han ZW, J. Appl. Polym. Sci., 124(2), 1050 (2012)

[6] Wolfe JF, Arnold FE, Macromolecules., 14, 909 (1981)

[7] Wolfe JF, Loo BH, Arnold FE, Macromolecules., 14, 915 (1981)

[8] Wu GM, Hung CH, You JH, Liu SJ, J. Polym. Res., 11, 31 (2004)

[9] Wu GM, Chang CH, Vacuum., 81, 1159 (2007)

[10] Chen P, Zhang CS, Zhang XY, Wang BC, Li W, Lei QQ, Appl. Surf. Sci., 255(5), 3153 (2008)

[11] Liu DD, Hu J, Zhao YM, Zhou XS, Ning P, Wang Y, J. Appl. Polym. Sci., 102(2), 1428 (2006)

[12] Andreopoulos AG, Tarantili PA, J. Elastom. Plast., 30, 118 (1998)

[13] Zhang CH, Huang YD, Zhao YD, Mater. Chem. Phys., 92(1), 245 (2005)

[14] Guan Y, Mao YH, Kong OM, Zeng XF, Zhu PX, Color.Technol., n/a (2013)

[15] Schuler MJ, Remington WR, Discuss. Faraday Soc., 16, 201 (1954)

[16] Glenz O, Beckmann W, Wulder W, J. Soc. Dyers Colour., 75, 141 (1959)

[17] Patterson D, Sheldon RP, T. Faraday Soc., 55, 1254 (1959)

[18] Ladavos AK, Katsoulidis AP, Iosifidis A, Triantafyllidis KS, Pinnavaia TJ, Pomonis PJ, Micropor. Mesopor. Mater., 151, 126 (2012)

[19] Barrett EP, Joyner LG, Halenda PP, J. Am. Chem. Soc., 73, 373 (1951)

[20] Passe-Coutrin N, Altenor S, Cossement D, Jean-Marius C, Gaspard S, Micropor. Mesopor. Mater., 111, 517 (2008)

[21] Mao YH, Guan Y, Zheng QK, Feng XN, Wang XX, Cellulose., 18, 271 (2011)

[22] Chiou MS, Li HY, Chemosphere., 50, 1095 (2003)

[23] Aspland JR, Bird CL, J. Soc. Dyers Colour., 77, 9 (1961)

[24] Gerber H, J. Soc. Dyers Colour., 110, 375 (1994)

[25] Kim TK, Son YA, Lim YJ, Dyes Pigm., 72, 246 (2007)

[26] Bird CL, Harris MP, J. Soc. Dyers Colour., 73, 199 (1957)

[27] Park KH, Casetta M, Koncar V, Color. Technol., 118, 319 (2002)

[28] Vickerstaff T, The physical chemistry of dyeing, London, Oliver & Boyd (1954)

[29] Chairat M, Rattanaphani S, Bremner JB, Rattanaphani V, Dyes Pigm., 64, 231 (2005)

[30] Chairat M, Rattanaphani S, Bremner JB, Rattanaphani V, Dyes Pigm., 76, 435 (2008)

[31] Chiou MS, Li HY, J. Hazard. Mater., 93(2), 233 (2002)

[32] Rattee ID, Breuer MM, The physical chemistry of dye adsorption, London, Academic Press (1974)

[33] Crank J, The mathematics of diffusion, London, Oxford University Press (1975)