Journal of Industrial and Engineering Chemistry, Vol.19, No.5, 1525-1534, September, 2013
Residence time distribution analysis and optimization of photocatalysis of phenazopyridine using immobilized TiO2 nanoparticles in a rectangular photoreactor
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Optimization of photocatalytic degradation of phenazopyridine (PhP) under UV light irradiation using immobilized TiO2 nanoparticles was studied. The effect of operational parameters was investigated using response surface methodology (RSM). Maximum removal efficiency was achieved at the optimum conditions: initial drug concentration of 10 mg/L, UV light intensity of 47 W/m2, flow rate of 200 mL/min, and reaction time of 150 min. The residence time distribution (RTD) analysis was studied to find the effect of flow rate on the drug removal efficiency. The tracer (PhP) pulse injection response was studied with UV-vis measurements and was used to prepare RTD curves.
Keywords:TiO2 nanoparticles;Photocatalyst;Pharmaceutical wastewater;Response surface methodology;Flow pattern
- Zyoud AH, Zaatar N, Saadeddin I, Ali C, Park D, Campet G, Hilal HS, J. Hazard. Mater., 173(1-3), 318 (2010)
- Hilal HS, Al-Nour GYM, Zyoud A, Helal MH, Saadeddin I, Solid State Science., 12, 578 (2010)
- Huerta-Fontela M, Galceran MT, Ventura F, Water Research., 45, 1432 (2011)
- Khataee AR, Kasiri MB, J. Mol. Catal. A-Chem., 328(1-2), 8 (2010)
- Khataee AR, Fathinia M, Aber S, Ind. Eng. Chem. Res., 49(24), 12358 (2010)
- Gandhi VG, Mishra MK, Rao MS, Kumar A, Joshi PA, Shah DO, J. Ind. Eng. Chem., 17(2), 331 (2011)
- Song SH, Kang MS, J. Ind. Eng. Chem., 14(6), 785 (2008)
- Khataee AR, Mansoori GA, Nanostructured titanium dioxide materials: properties, preparation and applications, World Scientific Publishing Co., Singapore (2011)
- Sahle-Demessie E, Bekele SF, Pillai UR, Catal. Today, 88(1-2), 61 (2003)
- Khataee AR, Fathinia M, Aber S, Zarei M, J. Hazard. Mater., 181(1-3), 886 (2010)
- Gholami RM, Mousavi SM, Borghei SM, J. Ind. Eng. Chem., 18(1), 218 (2012)
- Yoong CC, Nyuk Ling C, Yus Aniza Y, Chung Lim RATL, Industrial Crops and Products., 40, 247 (2012)
- Khataee AR, Zarei M, Fathinia M, Jafari MK, Desalination, 268(1-3), 126 (2011)
- Jeon SW, Lee JY, Lee JH, Kang SW, Park CH, Kim SW, J. Ind. Eng. Chem., 14(3), 338 (2008)
- Fathinia M, Khataee AR, Zarei M, Aber S, J. Mol. Catal. A-Chem., 333(1-2), 73 (2010)
- Moreira RM, Pinto AMF, Mesnier R, Leclerc JP, Applied Radiation and Isotopes., 65, 419 (2007)
- Fogler SH, Elements of chemical reaction engineering, fourth ed., Prentice-Hall International, New Jersey (1992)
- Waje SS, Patel AK, Thorat BN, Mujumdar AS, Drying Technology., 25, 249 (2007)
- Yang M, Zhu JJ, Mater. Res. Bull., 40(2), 265 (2005)
- Zarei M, Niaei A, Salari D, Khataee A, J. Hazard. Mater., 173(1-3), 544 (2010)
- Habibi B, Khataee AR, Desalination and Water Treatment., 243 (2010)
- Noordin MY, Venkatesh VC, Sharif S, Elting S, Abdullah A, Journal of Materials Processing Technology., 145, 46 (2004)
- Marques J, Vilareal H, Alfaia A, Ribeiro M, Food Chemistry., 105, 504 (2007)
- Ribeiro MHL, Afonso C, Vila-Real HJ, Alfaia AJ, Ferreira L, LWT Food Science and Technology., 43, 482 (2010)
- Khataee AR, Fathinia M, Aber S, Chem. Eng. Res. Des., 89(10A), 2110 (2011)
- Zarei M, Khataee AR, Ordikhani-Seyedlar R, Fathinia M, Electrochim. Acta, 55(24), 7259 (2010)
- Flury M, Wai NN, Reviews of Geophysics., 41, 1002 (2003)
- Kruse A, Lietz C, Chem. Eng. Technol., 26(11), 1119 (2003)
- Wanchoo RK, Kaur N, Bansal M, Thakur A, Chem. Eng. Commun., 194(10-12), 1503 (2007)
- Plugatyr A, Svishchev IM, J. Supercrit. Fluids, 44(1), 31 (2008)
- Hornung CH, Mackley MR, Chem. Eng. Sci., 64(17), 3889 (2009)
- Jovic´ F, Kosar V, Tomasˇic´ V, Gomzi Z, Chemical Engineering Research and Design., 90, 1297 (2011)
- Martin AD, Chem. Eng. Sci., 55(23), 5907 (2000)
- Puaux JP, Bozga G, Ainser A, Chem. Eng. Sci., 55(9), 1641 (2000)
- Gavrilescu M, Tudose RZ, Chem. Eng. Process., 38(3), 225 (1999)
- Kumar A, Ganjyal GM, Jones DD, Hanna MA, Journal of Food Engineering., 84, 441 (2008)
- van Howelingen AJ, Van der Merwe W, Wales N, Heydenrych M, Nicol W, Chem. Eng. Res. Des., 87(5A), 677 (2009)
- Nauman EB, Buffham BA, Mixing in continuous flow systems, John Wiley & Sons, New York (1983)
- Alkhaddar RM, Higgins PR, Phipps DA, Andoh RYG, Urban Water., 3, 17 (2001)
- Dijkstra MFJ, Panneman HJ, Winkelman JGM, Kelly JJ, Beenackers AACM, Chem. Eng. Sci., 57(22-23), 4895 (2002)
- Mehrotra K, Yablonsky GS, Ray AK, Chemosphere., 60, 1427 (2005)
- Mozia S, Tomaszewska M, Morawski AW, Dyes and Pigments., 75, 60 (2007)