화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.19, No.5, 1708-1714, September, 2013
DOI10.1016/j.jiec.2013.02.010  Export Citation
The effect of molecular solvents on the viscosity, conductivity and ionicity of mixtures containing chloride anion-based ionic liquid
Qiwei Yang, Kun Yu, Huabin Xing†, Baogen Su, Zongbi Bao, Yiwen Yang, and Qilong Ren
  • Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
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Chloride anion-based ionic liquids (ILs) have unique importance among various ILs. Nevertheless, they are usually very viscous, and the study on their mixtures with molecular solvent is important for their practical application. In this work, the viscosities and conductivities of the binary mixtures of 1-butyl-3-methylimidazolium chloride and several protic/aprotic solvents were measured, and the underlying information about intermolecular interaction and microscopic structure was discussed. The result showed that the molecular solvents which have relatively high dielectric constant and hydrogen-bond acidity will be more efficient in promoting the dissociation of chloride anion-based ILs and improving the transport properties of corresponding applications.
Keywords:Ionic liquid;Mixture;Viscosity;Conductivity;Ionicity
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