올리고글리세롤 모노라우레이트류의 합성에 관한 연구

강태준; 남기대; 김유옥; 윤영균; 김상춘

Journal of the Korean Industrial and Engineering Chemistry, Vol.4, No.3, 505-514, September, 1993

Export Citation

올리고글리세롤 모노라우레이트류의 합성에 관한 연구

The Synthesis of Oligoglycerol Monolaurates

강태준, 남기대, 김유옥, 윤영균, 김상춘

초록

올리고글리세롤 모노라우레이트 에스테르류를 단계적인 합성 방법으로 monoglycerol monolaurate, diglycerol monolaurate, symmetrical triglycerol monolaurate 및 symmetrical tetraglycerol monolaurate 등을 85∼95%의 높은 수율로 각각 제조하였다. 그리고 이 화합물들에 대한 TLC 및 관크로마토그래피를 행하여 순수한 물질로 잘 분리 정제하였고, IR 및 ¹H NMR로 구조를 확인하였다.

Defined oligoglycerol monolaurate esters were synthesized by means of step by step synthesis methods, and monoglycerol monolaurate, diglycerol monolaurate, symmetrical triglycerol monolaurate and symmetrical tetraglycerol monolaurate were obtained in a rate of 85∼95% yields. All the reacted products could be separated by means of column and thin layer chromatography, and the structure of products has been analyzed with IR, ¹H NMR spectra respectively.

[References]

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[1] Babayan VK, Kaufan TG, Lehman H, Tkaczak RJ, J. Soc. Cosmet. Sci., 15, 473 (1964)

[2] McIntyre RT, JAOCS, 56, 835A (1979)

[3] Stetzler RS, Smullin CF, Anal. Chem., 34, 194 (1962)

[4] Zlatanos SN, Sagredos AN, Papageorgiou VP, JAOCS, 62, 1575 (1985)

[5] Wachs W, Tenside, 4, 40 (1967)

[6] Kester EB, Gaiser CJ, Lazar ME, J. Org. Chem., 3, 550 (1943)

[7] Maerker G, Carmichael JF, Port WS, J. Org. Chem., 26, 2681 (1961)

[8] Maerker G, Saggese EJ, Port WS, JAOCS, 38, 194 (1961)

[9] Young HH, Black HC, J. Am. Chem. Soc., 60, 2803 (1983)

[10] Fisher W, Chem. Tech., 8, 343 (1980)

[11] Hilditch TP, Rigg JG, J. Chem. Soc., 1974 (1935)