알루미늄용 산성탈지제의 제조와 그의 특성화

박은경; 함현식; 박홍수

Journal of the Korean Industrial and Engineering Chemistry, Vol.4, No.3, 530-536, September, 1993

Export Citation

알루미늄용 산성탈지제의 제조와 그의 특성화

Preparation of Acidic Degreasing Agent for Aluminum and Its Characterization

박은경, 함현식, 박홍수

초록

n-Octanoic acid, MJU-l00A, Tetronix T-701, POE(6)-2-ethylhexyl ether, Newpol PE-68, 솔비톨 및 인산 등을 블렌딩하여 산성탈지제(ADA)를 제조하였다. ADA로서 알루미늄 시료편을 택하여 여러 가지 물성시험을 해 본 결과, ADA-5의 농도 3wt%, 70℃의 조건에서 탈지율은 98%로서 양호한 탈지효과를, etching율은 0.277%로서 시판품 보다 더 낮은 etching율을 각각 나타내었다. 또한 ADA-5의 농도 20wt%, 65℃의 조건에서 제청율은 93%였고, Ross and Miles법과 Ross and Clark법에 의한 저기포력시험 결과 양호한 소포효과를 보여주었다.

Acidic degreasing agent(ADA) was prepared by blending n-octanoic acid, MJU-100A, Tetronix T-701, POE(6)-2-ethylhexyl ether, Newpol PE-68, sorbitol, and phosphoric acid. The physical properties of ADA tested with aluminum specimen showed the following results; when 3wt% ADA-5 was performed at 70℃, the degreasing rate was 98% which is comparitively good, and the percentage of etching was 0.277% which was found to be less than that of commercialized product. When 20wt% of ADA-5 was added at 65℃, the percentage of derusting was 93% and the good defoaming effect proved by following low foaming power tests respectively : Ross and Miles, and Ross and Clark methods.

[References]

Spring S, "Metal Cleaning," 1sted., Reinhold Publishing, New York (1963)
Mamiya F, "The Technology of Metal Cleaning," 1st ed., Maki-Shoten, Tokyo (1971)
Kimura M, Komaki M, Nakajima T, Nakahara H, Fukuda K, J. Am. Oil Chem. Soc., 67, 698 (1990)
Durham K, "Surface Activity and Detergency," 1st ed., Macmillan and Co., London (1961)
Davidson JB, Metal Finishing, 57, 64 (1959)
Jansen G, Tervoort J, Galvanotechnik, 73, 580 (1982)
Zange B, Galvanotechnik, 80, 2288 (1989)
Domashenko AM, Narkunskii SE, Nepomnyashchaya RI, Petrova AI, Prusikina LA, Chem. Pet. Eng., 26, 470 (1991)
Lutter W, Calvanotechnik, 83, 97 (1992)
Devenny D, Metallurgia, 53, 140 (1986)
Osipov VN, Isaev NI, Prot. Met., 25, 671 (1990)
Park EK, Park HS, Kim YK, J. Korean Ind. Eng. Chem., 4(2), 358 (1993)
Berdly B, Schonberg D, Snell FD, Soap, 32, 47 (1956)
Harris JC, Kanp RE, Yank WH, J. Electro. Chem. Soc., 97, 430 (1950)
Wrigley AN, Smith FD, Stirton AJ, J. Am. Oil Chem. Soc., 34, 39 (1957)
Osipow L, Snell FD, Finehler A, Ind. Eng. Chem., 48, 1454 (1956)
Holness H, J. Appl. Chem., 1, 158 (1951)
Ochi E, Aoki E, Jitsumu Hyomen Gijutsu, 32, 362 (1985)
Jpn. Oil and Fast Co., "Surfactant Handbook," 1st ed., Kogaku Tosho Co., Tokyo, 216 (1987)
Konno K, Kitahara A, J. Colloid Interface Sci., 41, 86 (1972)
Jpn. Oil and Fats Co., "Surfactant Handbook," 1st ed., Kogaku Tosho Co., Tokyo, 176 (1987)
Park EK, Park HS, J. Korean Fiber Soc., 30, 232 (1993)

[1] Spring S, "Metal Cleaning," 1sted., Reinhold Publishing, New York (1963)

[2] Mamiya F, "The Technology of Metal Cleaning," 1st ed., Maki-Shoten, Tokyo (1971)

[3] Kimura M, Komaki M, Nakajima T, Nakahara H, Fukuda K, J. Am. Oil Chem. Soc., 67, 698 (1990)

[4] Durham K, "Surface Activity and Detergency," 1st ed., Macmillan and Co., London (1961)

[5] Davidson JB, Metal Finishing, 57, 64 (1959)

[6] Jansen G, Tervoort J, Galvanotechnik, 73, 580 (1982)

[7] Zange B, Galvanotechnik, 80, 2288 (1989)

[8] Domashenko AM, Narkunskii SE, Nepomnyashchaya RI, Petrova AI, Prusikina LA, Chem. Pet. Eng., 26, 470 (1991)

[9] Lutter W, Calvanotechnik, 83, 97 (1992)

[10] Devenny D, Metallurgia, 53, 140 (1986)

[11] Osipov VN, Isaev NI, Prot. Met., 25, 671 (1990)

[12] Park EK, Park HS, Kim YK, J. Korean Ind. Eng. Chem., 4(2), 358 (1993)

[13] Berdly B, Schonberg D, Snell FD, Soap, 32, 47 (1956)

[14] Harris JC, Kanp RE, Yank WH, J. Electro. Chem. Soc., 97, 430 (1950)

[15] Wrigley AN, Smith FD, Stirton AJ, J. Am. Oil Chem. Soc., 34, 39 (1957)

[16] Osipow L, Snell FD, Finehler A, Ind. Eng. Chem., 48, 1454 (1956)

[17] Holness H, J. Appl. Chem., 1, 158 (1951)

[18] Ochi E, Aoki E, Jitsumu Hyomen Gijutsu, 32, 362 (1985)

[19] Jpn. Oil and Fast Co., "Surfactant Handbook," 1st ed., Kogaku Tosho Co., Tokyo, 216 (1987)

[20] Konno K, Kitahara A, J. Colloid Interface Sci., 41, 86 (1972)

[21] Jpn. Oil and Fats Co., "Surfactant Handbook," 1st ed., Kogaku Tosho Co., Tokyo, 176 (1987)

[22] Park EK, Park HS, J. Korean Fiber Soc., 30, 232 (1993)