Densities, rho, and excess molar volumes, V-m(E), for binary mixtures containing propylene carbonate + 10 chlorohydrocarbons (dichloromethane, 1,2-dichloroethane, 1,3-dichloropropane, 1,4-dichlorobuthane, 1,6-dichlorohexane, 1,10-dichlorodecane, 1,1,1-trichloroethane, 1,1,2,2-tetrachloroethane, trans-1,2-dichloroethene, and trichloroethene) have been measured at 298.15 K and at atmospheric pressure using an Anton Paar digital vibrating tube density meter. The results are fitted to the Redlich-Kister equation. The values of V-m(E) for the mixtures containing dichloroalkanes show an increasing trend with the increase of the chain length and vary from a minimum of -0.24 cm(3) . mol(-1) for dichloromethane up to a maximum of +0.31 cm(3) . mol(-1) for 1,10-dichlorodecane. The excess molar volumes for the other mixtures are negative over the entire range of composition. Results are qualitatively discussed in terms of molecular interactions.