Journal of Chemical and Engineering Data, Vol.41, No.4, 745-747, 1996
Vapor-Liquid-Equilibria for 1,1,1,2-Tetrafluoroethane Plus 1-Chloro-1,2,2,2-Tetrafluoroethane and 1-Chloro-1,2,2,2-Tetrafluoroethane Plus 1-Chloro-1,1-Difluoroethane Systems
Isothermal vapor-liquid equilibria were determined for two binary mixtures of refrigerants with a circulation type apparatus. The 1,1,1,2-tetrafluoroethane (HFC-134a) + 1-chloro-1,2,2,2-tetrafluoroethane (HCFC-124) system was studied at 296.45, 302.25, and 307.25 K. The 1-chloro-1,2,2,2-tetrafluoroethane (HCFC-124) + 1-chloro-1,1-difluoroethane (HCFC-142b) system was studied at 298.15 and 312.15 K. At each temperature, the pressure and vapor and liquid compositions were measured. Results were correlated with the Peng-Robinson equation of state.
Keywords:HIGH-PRESSURE;MIXTURES