화학공학소재연구정보센터
Journal of Chemical and Engineering Data, Vol.42, No.1, 132-136, 1997
Vapor-Liquid-Equilibria for the Binary-Systems of 1-Butanol with Some Halohydrocarbons at 40.0 and 101.3 kPa
Isobaric vapor-liquid equilibrium measurements at 40.0 and 101.3 kPa are reported for 1-butanol + chlorocyclohexane, + chlorobenzene, + bromocyclohexane, + bromobenzene. Some of the studied systems show minimum temperature azeotropes. The experimental data were tested for thermodynamic consistency and satisfactorily correlated with the Margules, Van Laar, Wilson, NRTL, and UNIQUAC equations. Predictions with the UNIFAC method and ASOG method were also obtained.