A facile and palladium-free process for the electroless plating on poly(vinyl chloride) (PVC) plastic has been demonstrated. The process is based on the Cu adsorption capacity of semi-interpenetrating polymer network (semi-IPN) hydrogel chemically bonded to PVC surface via a simple and one-step approach that applying a chitosan/polyethylene glycol/glutaraldehyde system under mild stirring at room temperature. Therefore, electroless plating can be achieved in the following three steps, namely: (1) the functionalization of PVC by the semi-IPN hydrogel film (2) the adsorption and formation of the catalyst Cu-0 on the PVC surface, and (3) the electroless nickel plating in plating bath. Batch adsorption experiments are conducted to determine the effects of pH, initial Cu2+ ions concentration and the dosage of crosslinking agent glutaraldehyde on copper adsorption and the surface resistance of the corresponding plated-PVC. The activated reaction progress and resulting nickel-phosphorus (Ni-P) layer were characterized by attenuated total reflection Fourier transform infrared, scanning electron microscopy, X-ray photoelectron spectroscopy, energy dispersive X-ray spectroscopy, and X-ray diffraction. The results show that the Cu nanoparticles chemisorbed on the functionalized PVC substrate, could effectively initial the subsequent electroless nickel plating; and a compact and continuous Ni-P layer with amorphous phase was successfully deposited on PVC by this process. Besides, the surface resistance of the plated-PVC as low as 0.5 a"broken vertical bar sq(-1) showed an excellent adhesion with the PVC substrate proved by Scotch-tape test.