Excess molar volumes for {1,4-dioxane + heptane, octane, nonane, and decane} at the temperatures 288.15 K, 298.15 K, and 308.15 K, excess molar enthalpies for {1,4-dioxane + heptane, octane, nonane, decane, dodecane, tetradecane, and hexadecane} at the temperature 298.15 K, and isobaric excess molar heat capacities for {1,4-dioxane + heptane, octane, nonane, and decane} at the temperature 298.15 K have been determined as a function of mole fraction. The magnitude of these experimental quantities is discussed in terms of the nature and type of intermolecular interactions in binary mixtures.